Mononuclear Nitrogen/sulfur-ligated Cobalt(II) Methoxide Complexes: Structural, EPR, Paramagnetic 1H NMR, and Electrochemical Investigations
Format of Original
The Royal Society of Chemistry
Original Item ID
The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic 1H NMR, and cyclic voltammetry.