Date of Award

Summer 1968

Document Type

Thesis - Restricted

Degree Name

Master of Science (MS)

Department

Electrical Engineering

First Advisor

Blumenthal, Robert N.

Second Advisor

Hirthe, Walter M.

Third Advisor

O'Brien, William J.

Abstract

Several previous Investigators have shown that gold rich Au-Pt alloys containing smalI amounts of iron exhibit an age hardening phenomenon. The change In hardness for these alloys has been reported as a function of composition, aging time, and aging temperature. A rod-shaped lntergranular precipitate has been observed in the aged alloys. Also, It is possible that an intragranular precipitate is formed. In this investigation, neutron diffraction and electron microprobe analysis were employed to determine the composition of the intergranular precipitate. The kinetics of precipitation in these alloys were followed using electrical resistance measurements as a function of alloy composition, aging time, and aging temperature. An empirical rate equation was employed to determine the rate Iimiting process occuring in these alloys and an empirical activation energy was obtained.

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