A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I)

Authors

Brendan J. Liddle, Marquette UniversityFollow
Sergey V. Lindeman, Marquette UniversityFollow
Daniel L. Reger, University of South Carolina
James R. Gardinier, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

2007

Publisher

American Chemical Society

Source Publication

Inorganic Chemistry

Source ISSN

0020-1669

Abstract

A simple, one-pot preparation of rhenium(I) σ-arylalkynyl complexes is reported using thallium(I) hexafluorophosphate as a halogen abstraction agent. This new route to rhenium σ-alkynyls enjoys higher yields compared to analogous preparations using silver salts by eliminating potential electrochemical degradation pathways.

Comments

Accepted version. Inorganic Chemistry, Vol. 46, No. 21 (2007): 8484-8486. DOI. © 2007 American Chemical Society. Used with permission.

Recommended Citation

Liddle, Brendan J.; Lindeman, Sergey V.; Reger, Daniel L.; and Gardinier, James R., "A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I)" (2007). Chemistry Faculty Research and Publications. 624.
https://epublications.marquette.edu/chem_fac/624