Title

A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I)

Document Type

Article

Language

eng

Publication Date

2007

Publisher

American Chemical Society

Source Publication

Inorganic Chemistry

Source ISSN

0020-1669

Abstract

A simple, one-pot preparation of rhenium(I) σ-arylalkynyl complexes is reported using thallium(I) hexafluorophosphate as a halogen abstraction agent. This new route to rhenium σ-alkynyls enjoys higher yields compared to analogous preparations using silver salts by eliminating potential electrochemical degradation pathways.

Comments

Inorganic Chemistry, Vol. 46, No. 21 (2007): 8484-8486. DOI.

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