Structure of 1,1-di(tert-butylperoxy)cyclohexane

Authors

A. Yu. Kosnikov, A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSRFollow
V. L. Antonovskii, A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSRFollow
Sergey Lindeman, Marquette UniversityFollow
Yuri T. Struchkov, A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSRFollow
E. V. Fedorova, Academy of Sciences of the USSR

Document Type

Article

Language

eng

Publication Date

2-1989

Publisher

Springer

Source Publication

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science

Source ISSN

0568-5230

Abstract

From the example of 1,1-di(tert-butylperoxy)cyclohexane it was shown that not only intramolecular steric interactions (the type of substituent at the O-O bond) but also the influence of crystal field forces have a substantial effect on the conformation of the peroxide group in the crystals of peroxyketals of cyclanes.

Comments

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science, Vol. 38, No. 2 (February 1898): 247-249. DOI.

Sergey Lindeman was affiliated with Institute of Chemical Physics, A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR at the time of publication.

Recommended Citation

Kosnikov, A. Yu.; Antonovskii, V. L.; Lindeman, Sergey; Struchkov, Yuri T.; and Fedorova, E. V., "Structure of 1,1-di(tert-butylperoxy)cyclohexane" (1989). Chemistry Faculty Research and Publications. 722.
https://epublications.marquette.edu/chem_fac/722