Two Alternative Pathways For The Interaction Of Hexacyanocyclopropane With Nucleophile

Authors

Oleg E. Nasakin, Chuvash State University
Petr M. Lukin, Chuvash State University
Evgenii V. Vershinin, Chuvash State University
Sergey Lindeman, Marquette UniversityFollow
Yurii T. Struchkov, Russian Academy of SciencesFollow

Document Type

Article

Language

eng

Publication Date

1994

Publisher

Elsevier

Source Publication

Mendeleev Communications

Source ISSN

0959-9436

Abstract

Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 was established by an X-ray crystallographic study.

Comments

Mendeleev Communications, Vol. 4, No. 5 (1994): 185-186. DOI.

Recommended Citation

Nasakin, Oleg E.; Lukin, Petr M.; Vershinin, Evgenii V.; Lindeman, Sergey; and Struchkov, Yurii T., "Two Alternative Pathways For The Interaction Of Hexacyanocyclopropane With Nucleophile" (1994). Chemistry Faculty Research and Publications. 823.
https://epublications.marquette.edu/chem_fac/823