(η⁵-1-substituted-pentadienyl) (tricarbonyl)iron(+1) Cations: Reactivity with Alkynyl Nucleophiles

Authors

William Donaldson, Marquette UniversityFollow
Muthukumar Ramaswamy, Marquette University

Document Type

Article

Language

eng

Publication Date

1989

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title compounds react with alkynyl cuprates via attack at the unsubstituted terminus to afford (η⁴-trans, cis-1,3,6-dienyne)Fe(CO)₃ complexes. The regioselectivity of this attack appears to be sterically controlled.

The title compounds react with alkynyl cuprates via attack at the unsubstituted pentadienyl terminus to afford (η⁴-trans, cis-1,3,6-dienyne)Fe(CO)₃complexes.

Comments

Tetrahedron Letters, Vol. 30, No. 11 (1989): 1339-1342. DOI.

Recommended Citation

Donaldson, William and Ramaswamy, Muthukumar, "(η⁵-1-substituted-pentadienyl) (tricarbonyl)iron(+1) Cations: Reactivity with Alkynyl Nucleophiles" (1989). Chemistry Faculty Research and Publications. 849.
https://epublications.marquette.edu/chem_fac/849