Title

5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) Cations: Reactivity with Alkynyl Nucleophiles

Document Type

Article

Language

eng

Publication Date

1989

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title compounds react with alkynyl cuprates via attack at the unsubstituted terminus to afford (η4-trans, cis-1,3,6-dienyne)Fe(CO)3 complexes. The regioselectivity of this attack appears to be sterically controlled.

The title compounds react with alkynyl cuprates via attack at the unsubstituted pentadienyl terminus to afford (η4-trans, cis-1,3,6-dienyne)Fe(CO)3complexes.

Comments

Tetrahedron Letters, Vol. 30, No. 11 (1989): 1339-1342. DOI.

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