Title

Concerning the Reaction of (η5-1-methoxycarbonylpentadienyl)(tricarbonyl)iron(+1) with Malonate Anion: A Structural Correction

Document Type

Article

Language

eng

Publication Date

1989

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title reaction was originally reported to afford the E,Z-η4-diene complex. Reexamination of the spectral data and decomplexation of the ligand indicates that the product is a σ-π-allyl complex.

The title reaction affords a σ-π-allyl complex, instead of an η4-diene complex as originally reported (Tetrahedron Lett., 1988, 1343).

Comments

Tetrahedron Letters, Vol. 30, No. 11 (1989): 1343-1344. DOI.

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