Chemical Switching Behaviour of Tricarbonylrhenium(I) Complexes of a New Redox Active ‘Pincer’ Ligand

Authors

Sarath Wanniarachchi, Marquette UniversityFollow
Brendan J Liddle, Marquette UniversityFollow
John Toussaint, Marquette University
Sergey Lindeman, Marquette UniversityFollow
Brian Bennett, Marquette UniversityFollow
James R. Gardinier, Marquette UniversityFollow

Document Type

Article

Language

eng

Format of Original

3 p.

Publication Date

4-7-2010

Publisher

The Royal Society of Chemistry

Source Publication

Dalton Transactions

Source ISSN

1477-9226

Original Item ID

doi: 10.1039/C001344G

Abstract

The structures and optoelectronic properties of tricarbonylrhenium(I) complexes of di(2-pyrazolyl-p-tolyl)amine in its neutral and deprotonated (uninegative amido) form were investigated. Reactions of the complexes with Brønsted acids or bases result in distinctive changes of colour and electrochemical activity owing to the non-innocent nature of the ligand.

Comments

Accepted version. Dalton Transactions, Vol. 39, No. 13 (April 7, 2010): 3167-3169. DOI. © 2010 Royal Society of Chemistry.Used with permission.

Brian Bennett was affiliated with the Medical College of Wisconsin at the time of publication.

Recommended Citation

Wanniarachchi, Sarath; Liddle, Brendan J; Toussaint, John; Lindeman, Sergey; Bennett, Brian; and Gardinier, James R., "Chemical Switching Behaviour of Tricarbonylrhenium(I) Complexes of a New Redox Active ‘Pincer’ Ligand" (2010). Physics Faculty Research and Publications. 109.
https://epublications.marquette.edu/physics_fac/109