The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2003

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The Charge-Transfer Motif in Crystal Engineering. Self-Assembly of Acentric (Diamondoid) Networks from Halide Salts and Carbon Tetrabromide as Electron-Donor/Acceptor Synthons, Sergey V. Lindeman, Jürgen Hecht, and Jay K. Kochi

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Enantioselective Synthesis of the C7-C24 Segment of Macrolactin A, Shukun Li and William Donaldson

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Synthesis of (+)-decarestrictine L, Julie Lukesh and William Donaldson

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The Role of the Dielectric Barrier in Narrow Biological Channels: a Novel Composite Approach to Modeling Single-channel Currents, Artem B. Mamonov, Rob D. Coalson, Abraham Nitzan, and Maria G. Kurnikova

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Molecular Recognition of NO/NO+ via Multicenter (Charge-Transfer) Binding to Bridged Diarene Donors. Effect of Structure on the Optical Transitions and Complexation Thermodynamics, Sergiy V. Rosokha, Sergey V. Lindeman, Rajendra Rathore, and Jay K. Kochi

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Intervalence (Charge-Resonance) Transitions in Organic Mixed-Valence Systems. Through-Space versus Through-Bond Electron Transfer between Bridged Aromatic (Redox) Centers, D.-L. Sun, Sergiy V. Rosokha, Sergey V. Lindeman, and Jay K. Kochi

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Exfoliated Poly(Methyl Methacrylate) and Polystyrene/ Nanocomposites Occur when the Clay Cation Contains a Vinyl Monomer, Shengpei Su and Charles A. Wilkie

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A Stibonium-Modified Clay and its Polystyrene Nanocomposite, Dongyan Wang and Charles A. Wilkie

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In situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites, Dongyan Wang and Charles A. Wilkie

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Iron-mediated Preparation of Vinylcyclopropanes. Scope, Mechanism, and Applications, Young K. Yun, Kamil Godula, Yeyu Cao, and William A. Donaldson

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Preparation and flammability properties of polyethylene-clay nanocomposites, Jinguo Zhang and Charles A. Wilkie

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Flame Retardancy of Polystyrene Nanocomposites Based on an Oligomeric Organically-Modified Clay Containing Phosphate, Xiaoxia Zheng and Charles A. Wilkie

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Nanocomposites Based on Poly (ε-Caprolactone) (PCL)/Clay Hybrid: Polystyrene, High Impact Polystyrene, ABS, Polypropylene and Polyethylene, Xiaoxia Zheng and Charles A. Wilkie

Submissions from 2002

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Structurally Distinct Active Sites in the Copper(II)-Substituted Aminopeptidases from Aeromonas proteolytica and Escherichia coli, Brian Bennett, William E. Antholine, Ventris M. D'Souza, Guanjing Chen, Leila Ustinyuk, and Richard C. Holz

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Hydrolysis of Thionopeptides by the Aminopeptidase from Aeromonas proteolytica:  Insight into Substrate Binding, David L. Bienvenue, Danuta M. Gilner, and Richard C. Holz

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The Aminopeptidase from Aeromonas proteolytica can Function as an Esterase, David L. Bienvenue, Rebecca S. Matthew, Dagmar Ringe, and Richard C. Holz

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Enantioselective synthesis of the C11–C17 segment of soraphen A1α via organoiron methodology, Yeyu Cao, Ahmad F Eweas, and William Donaldson

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Three-Dimensional Structure of the Complexin/SNARE Complex, Xiaocheng Chen, Diana R. Tomchick, Evgueni Kovriguine, Demet Araç, Mischa Machius, Thomas C. Südhof, and Josep Rizo

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Electrochemistry and Spectroscopy of Sulfate and Thiosulfate Complexes of Iron Porphyrins, Philip Walter Crawford and Michael D. Ryan

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The 1.20 Å Resolution Crystal Structure of the Aminopeptidase from Aeromonas proteolytica Complexed with Tris: A Tale of Buffer Inhibition, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Richard C. Holz, Gregory A. Petsko, and Dagmar Ringe

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Kinetic and Structural Characterization of Manganese(II)-Loaded Methionyl Aminopeptidases, Ventris M. D'Souza, Sabina I. Swierczek, Nathaniel J. Cosper, Lu Meng, Shane Ruebush, Alicja J. Copik, Robert A. Scott, and Richard C. Holz

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An XPS Investigation of Thermal Degradation and Charring of PMMA Clay Nanocomposites, Jianxin Du, Jin Zhu, Charles A. Wilkie, and Jiangqi Wang

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Synthetic studies directed toward the phorboxazoles: preparation of the C3–C15 bisoxane segment and two stereoisomers, Patrick Bernard Greer and William Donaldson

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The Aminopeptidase From Aeromonas proteolytica: Structure and Mechanism of Co-Catalytic Metal Centers Involved in Peptide Hydrolysis, Richard C. Holz

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Crown Ether-Modified Clays and their Polystyrene Nanocomposites, Hongyang Jao, Jin Zhu, Alexander B. Morgan, and Charles A. Wilkie

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Doming Modes and Dynamics of Model Heme Compounds, Dennis D. Klug, Marek Z. Zgierski, John S. Tse, Zhenxian Liu, James R. Kincaid, Kazimierz Czarnecki, and Russell J. Hemley

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X-ray Structure Analysis and the Intervalent Electron Transfer in Organic Mixed-Valence Crystals with Bridged Aromatic Cation Radicals, Sergey V. Lindeman, Sergiy V. Rosokha, Duoli Sun, and Jay K. Kochi

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Overexpression and Divalent Metal Binding Properties of the Methionyl Aminopeptidase from Pyrococcus furiosus, Lu Meng, Shane Ruebush, Ventris M. D'Souza, Alicja J. Copik, Susumu Tsunasawa, and Richard C. Holz

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Steric Hindrance as a Mechanistic Probe for Olefin Reactivity:  Variability of the Hydrogenic Canopy over the Isomeric Adamantylideneadamantane/Sesquihomoadamantene Pair (A Combined Experimental and Theoretical Study), Rajendra Rathore, Sergey V. Lindeman, C.-J. Zhu, T. Mori, R. Schleyer, and Jay K. Kochi

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Novel bis-arene (Sandwich) Complexes with NO+ Acceptor. Isolation, X-ray Crystallography and Electronic Structure, Sergiy V. Rosokha, Sergey V. Lindeman, and Jay K. Kochi

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Polystyrene/Graphite Nanocomposites: Effect on Thermal Stability, Fawn Marie Uhl and Charles A. Wilkie

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Molecular Structures of the Metastable Charge-Transfer Complexes of Benzene (and Toluene) With Bromine as the Pre-Reactive Intermediates in Electrophilic Aromatic Bromination, Alexandr V. Vasilyev, Sergey V. Lindeman, and Jay K. Kochi

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Synthesis of cyclopropanes via organoiron methodology: stereoselective preparation of cis-2-(2’-carboxycyclopropyl)glycine, Nathaniel J Wallock and William Donaldson

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Melt blending preparation of PVC-sodium clay nanocomposites, Dongyan Wang, Daniel Parlow, Qiang Yao, and Charles A. Wilkie

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Preparation of PVC- Clay Nanocomposites by Solution Blending, Dongyan Wang and Charles A. Wilkie

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A Comparison Of Various Methods For The Preparation Of Polystyrene And Poly(Methyl Methacrylate) Nanocomposites, Dongyan Wang, Jin Zhu, Qiang Yao, and Charles A. Wilkie

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An XPS study of the thermal degradation of polystyrene-clay nanocomposites, Jianqi Wang, Jianxin Du, Jin Zhu, and Charles A. Wilkie

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Fire Retardant Halogen-Antimony-Clay Synergism in Polypropylene Layered Silicate Nanocomposites, Marco Zanetti, Giovanni Camino, Domenico Canavese, Alexander B. Morgan, Frank K. Lamelas, and Charles A. Wilkie

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Silicon-Methoxide-Modified Clays and their Polystyrene Nanocomposites, Jin Zhu, Paul Start, Kenneth A. Mauritz, and Charles A. Wilkie

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Thermal stability and flame retardancy of poly(methyl methacrylate)-clay nanocomposites, Jin Zhu, Paul Start, Kenneth A. Mauritz, and Charles A. Wilkie

Submissions from 2001

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Structural Evidence That the Methionyl Aminopeptidase from Escherichia coli Is a Mononuclear Metalloprotease, Nathaniel J. Cosper, Ventris M. D'Souza, Robert A. Scott, and Richard C. Holz

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Synthesis of cyclopropane containing natural products, William Donaldson

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An Efficient and Simple Synthesis of Optically Pure Tricarbonyl(methyl 6-oxo-2,4-hexadienoate)iron, Kamil Godula, Heiko Bärmann, and William A. Donaldson

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Synthesis of cyclopropanes via organoiron methodology: preparation of 2-(2′-carboxy-3′-ethylcyclopropyl)glycine, Kamil Godula and William Donaldson

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An XPS Investigation of Thermal degradation and Charring of Cross-linked Polyisoprene and Polychloroprene, JIanwei Hao, Charles A. Wilkie, and Jiangqi Wang

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Reactivity of acyclic (pentadienyl)iron(1+) cations with weak carbon nucleophiles, M. Azad Hossain, Myung-Jong Jin, and William Donaldson

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Diels−Alder Topochemistry via Charge-Transfer Crystals:  Novel (Thermal) Single-Crystal-to-Single-Crystal Transformations, J. H. Kim, S. M. Hubig, Sergey V. Lindeman, and Jay K. Kochi

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Charge-Transfer Forces in the Self-Assembly of Heteromolecular Reactive Solids:  Successful Design of Unique (Single-Crystal-to-Single-Crystal) Diels−Alder Cycloadditions, J. H. Kim, Sergey V. Lindeman, and Jay K. Kochi

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Electron Redistribution of Aromatic Ligands in (Arene)Cr(CO)3 Complexes. Structural (Bond-Length) Changes as Quantitative Measures, P. Le Maguères, Sergey V. Lindeman, and Jay K. Kochi

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by l-Leucinephosphonic Acid. Spectroscopic and Crystallographic Characterization of the Transition State of Peptide Hydrolysis, Carin Stamper, Brian Bennett, Tanya Edwards, Richard C. Holz, Dagmar Ringe, and Gregory A. Petsko

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Intramolecular (Electron) Delocalization Between Aromatic Donors and their Tethered Cation–Radicals. Application of Electrochemical and Structural Probes, Duoli Sun, Sergey V. Lindeman, Rajendra Rathore, and Jay K. Kochi

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Photooxidation of Polymeric-inorganic nanocomposites: Chemical, Thermal Stability and Fire Retardancy Investigations, Adams Tidjani and Charles A. Wilkie

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The Thermal Stability Of Cross-Linked Polymers: Methyl Methacrylate With Divinylbenzene and Styrene With Dimethacrylates, Fawn Marie Uhl, Galina F. Levchik, Sergei V. Levchik, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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Noncovalent Binding of the Halogens to Aromatic Donors. Discrete Structures of Labile Br2 Complexes with Benzene and Toluene, Alexandr V. Vasilyev, Sergey V. Lindeman, and Jay K. Kochi

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PVC-Clay nanocomposites: Preparation, Thermal and Mechanical Properties, Dongyan Wang, Daniel Parlow, Qiang Yao, and Charles A. Wilkie

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XPS Characterization of Friedel-Crafts Cross-Linked Polystyrene, Jiangqi Wang, Jianxin Du, Hongyang Yao, and Charles A. Wilkie

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Electrochemistry and spectroelectrochemistry of iron porphyrins in the presence of nitrite, Zhongcheng Wei and Michael D. Ryan

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Graft Copolymerization as a Tool for Flame Retardancy, Charles A. Wilkie

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Fire Retardancy in 2001, Gordon L. Wilson and Charles A. Wilkie

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Cross-linking of Polystyrene by Friedel-Crafts Chemistry: Reaction of p-Hydroxymethylbenzyl Chloride with Polystyrene, Hongyang Yao, Michael A. McKinney, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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Cross-Linking of Polystyrene by Friedel-Crafts Chemistry: A Review, Hongyang Yao and Charles A. Wilkie

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Thermal Degradation Of PVC In The Presence Of Polystyrene, Qiang Yao and Charles A. Wilkie

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Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation, Young K. Yun, Heiko Bärmann, and William Donaldson

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Fire Properties of Polystyrene-Clay Nanocomposites, Jin Zhu, Alexander B. Morgan, Frank K. Lamelas, and Charles A. Wilkie

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Studies on the mechanism by which the formation of nanocomposites enhance thermal stability, Jin Zhu, Fawn Marie Uhl, Alexander B. Morgan, and Charles A. Wilkie

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Recent Studies on Thermal Stability and Flame Retardancy of Polystyrene-Nanocomposites, Jin Zhu, Fawn Marie Uhl, and Charles A. Wilkie

Submissions from 2000

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Development of Organoiron Methodology for Preparation of the Polyene Natural Product Macrolactin A, Heiko Bärmann, Vadapalli Prahlad, Chunlin Tao, Young K. Yun, Zhi Wang, and William Donaldson

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by l-leucinethiol: Kinetic and Spectroscopic Characterization of a Slow, Tight-binding Inhibitor–enzyme Complex, David L. Bienvenue, Brian Bennett, and Richard C. Holz

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Stoichiometric Applications of Acyclic p-Organoiron Complexes to Organic Synthesis, William Donaldson

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Reaction of Alkynes with Tetracarbonyl[Methoxy(2,4-Dimethoxyphenyl)Carbene]chromium: A Formal Synthesis of 7-Methoxyeleutherin, Karl Heinz Dötz, William Donaldson, and Werner Sturm

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Divalent Metal Binding Properties of the Methionyl Aminopeptidase from Escherichia coli, Ventris M. D'Souza, Brian Bennett, Alicja J. Copik, and Richard C. Holz

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Phorboxazole synthetic studies: the C3–C15 bis-oxane segment, Patrick Bernard Greer and William Donaldson

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Charge-Transfer Bonding in Metal–Arene Coordination, S. M. Hubig, Sergey V. Lindeman, and Jay K. Kochi

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Thermal degradation of Cross-Linked Polyisoprene and Polychloroprene, David D. Jiang, Galina F. Levchik, Sergei V. Levchik, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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On the Stabilizing Action of Protein Denaturants: Acetonitrile Effect on Stability of Lysozyme in Aqueous Solutions, Evgueni Kovriguine and Sergey A. Potekhin

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Char Formation, Sergei V. Levchik and Charles A. Wilkie

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Electrophilic Aromatic Nitrosation. Isolation and X-ray Crystallography of the Metastable NO+ Complex With Nitrosoarene, Sergey V. Lindeman, E. Bosch, and Jay K. Kochi

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Silver(I) Complexation of (Poly)aromatic Ligands. Structural Criteria for Depth Penetration into cis-Stilbenoid Cavities, Sergey V. Lindeman, Rajendra Rathore, and Jay K. Kochi

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Novel Charge-Transfer Materials via Cocrystallization of Planar Aromatic Donors and Spherical Polyoxometalate Acceptors, P. Le Maguères, S. M. Hubig, Sergey V. Lindeman, P. Peya, and Jay K. Kochi

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Novel (Heteromolecular) π-Complexes of Aromatic Cation Radicals. Isolation and Structural Characterization, P. Le Maguères, Sergey V. Lindeman, and Jay K. Kochi

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Reaction of tricarbonyl(dienal)iron complexes with B-allyldiisopinocampheylborane, Vadapalli Prahlad, Abdel-Aziz S. El-Ahl, and William Donaldson

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Polybutadiene Cross-Linked With Various Diols – Effect On Thermal Stability, Fawn Marie Uhl, Michael A. McKinney, and Charles A. Wilkie

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Cross-linking of Polystyrene by Friedel-Crafts Chemistry: Multi-functional Additives, Hongyang Yao, Jin Zhu, Michael A. McKinney, and Charles A. Wilkie

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How does Cross-Linking Effect the Thermal Stability of Polyisoprene, Qiang Yao and Charles A. Wilkie

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Thermal and Fire Studies on Polystyrene-Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 1999

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Thermal Decomposition and Combustion of γ-irradiated Polyamide 6 Containing Phosphorus Oxynitride or Phospham, A. I. Balabanovich, Sergei V. Levchik, Galina F. Levchik, W. Schnabel, and Charles Wilkie

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1-Butaneboronic Acid Binding to Aeromonas proteolytica Aminopeptidase:  A Case of Arrested Development, Carin C. De Paola, Brian Bennett, Richard C. Holz, Dagmar Ringe, and Gregory A. Petsko

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The Methionyl Aminopeptidase from Escherichia coli Can Function as an Iron(II) Enzyme, Ventris M. D'Souza and Richard C. Holz

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Synthesis and Reactivity of Acyclic (pentadienyl)iron(1+) Cations: Model Studies for the Preparation of the 8E,10Z,16E,18E-Tetraene Segment of Macrolactin A, Abdel-Aziz S. El-Ahl, Young Yun, and William Donaldson

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An XPS Study of the Radiation-induced Effect on the Thermal Degradation and Charring of Butadiene and its Copolymers, JIanwei Hao, Shaoli Wu, Charles Wilkie, and Jianqi Wang

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1H NMR Studies on the CuA Center of Nitrous Oxide Reductase from Pseudomonas stutzeri, Richard C. Holz, Marcela L. Alvarez, Walter G. Zumft, and David M. Dooley

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Slow-Binding Inhibition of the Aminopeptidase from Aeromonas proteolytica by Peptide Thiols: Synthesis and Spectroscopic Characterization, Kristi M. Huntington, David L. Bienvenue, Yaoming Wei, Brian Bennett, Richard C. Holz, and Dehua Pei

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Thermal Decomposition of Cross-linked Polybutadiene and its Copolymers, David D. Jiang, Galina F. Levchik, Sergei V. Levchik, and Charles Wilkie

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TGA/FTIR Studies on the Thermal Degradation of some Polymeric Sulfonic and Phosphonic Acids and Their Sodium Salts, David D. Jiang, Qiang Yao, Michael A. McKinney, and Charles Wilkie

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Use of Evolutionary Factor Analysis in the Spectroelectrochemistry of Escherichia coli Sulfite Reductase Hemoprotein and a Mo/Fe/S Cluster, Robert L. Keesey and Michael D. Ryan

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Thermal Degradation of Polystyrene, Poly(1,4-butadiene) and Copolymers of Styrene and 1,4-butadiene Irradiated Under Air or Argon with 60Co-γ-rays, W. Schnabel, Galina F. Levchik, Charles Wilkie, David D. Jiang, and Sergei V. Levchik

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Visible and Resonance Raman Spectra of Low Valent Iron Porphyrins, Chathra De Silva, Kazimierz Czarnecki, and Michael D. Ryan

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by Aliphatic Alcohols. Characterization of the Hydrophobic Substrate Recognition Site, Leila Ustynyuk, Brian Bennett, Tanya Edwards, and Richard C. Holz

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Cross-linking of Polystyrene by Friedel–Crafts Chemistry to Improve Thermal Stability, Zhitao Wang, David D. Jiang, Michael A. McKinney, and Charles Wilkie

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Further Studies on Fire Retardant Polystyrene by Friedel–Crafts Chemistry, Zhitao Wang, David D. Jiang, Charles Wilkie, and Jeffery W. Gilman