The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2012

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Visible and Infrared Spectroelectrochemistry of Cobalt Porphinones and Porphinediones, Florentina Tutunea and Michael D. Ryan

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Syntheses and Electronic Properties of Rhodium(III) Complexes Bearing a Redox-Active Ligand, Sarath Wanniarachchi, Brendan J Liddle, Brandon Kizer, Jeewantha S. Hewage, Sergey Lindeman, and James R. Gardinier

Submissions from 2011

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Analysis of Binding Site Hot Spots on the Surface of Ras GTPase, Greg Buhrman, Casey O'Connor, Brandon Zerbe, Bradley M. Kearney, Raeanne Napoleon, Elizaveta A. Kovrigina, Sandor Vajda, Dima Kozakov, Evgueni Kovriguine, and Carla Mattos

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Removal of 2,4-dichlorophenoxyacetic Acid by Calcined Zn–Al–Zr Layered Double Hydroxide, Allen Chaparadza and Jeanne Hossenlopp

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Calcium Carbonate and Ammonium Polyphosphate-based Flame Retardant Composition for Polypropylene, Sarang Deodhar, Kadhiravan Shanmuganathan, Qinguo Fan, Charles A. Wilkie, Maurius C. Costache, Nicholas A. Dembsey, and Prabir K. Patra

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Alteration of Hydrogen Bonding in the Vicinity of Histidine 48 Disrupts Millisecond Motions in RNase A, Nicolet Doucet, Gennady Khirich, Evgueni Kovriguine, and J. Patrick Loria

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Complete Determination of the Pin1 Catalytic Domain Thermodynamic Cycle by NMR Lineshape Analysis, Alexander I. Greenwood, Monique J. Rogals, Soumya De, Kun Ping Lu, Evgueni Kovriguine, and Linda K. Nicholson

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Stereoselective Catalytic Synthesis of Tetrasubstituted Olefins from the Intermolecular Conjugate Addition of Simple Alkenes to α,β-Unsaturated Carbonyl Compounds, Ki Hyeok Kwon, Do W. Lee, and Chae S. Yi

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Reactivity of acyclic (pentadienyl)iron(1+) cations: Synthetic studies directed toward the frondosins, Do W. Lee, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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Fire Performance of Flame Retardant Polypropylene and Polystyrene Composites Screened with Microscale Combustion Calorimetry, Hongdian Lu and Charles A. Wilkie

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Defining CYP3A4 Structural Responses to Substrate Binding. Raman Spectroscopic Studies of a Nanodisc-incorporated Mammalian Cytochrome P450, Piotr J. Mak, Ilia G. Denisov, Yelena V. Grinkova, Stephen G. Sligar, and James R. Kincaid

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Pyrazolyl Methyls Prescribe the Electronic Properties of Iron(II) Tetra(pyrazolyl)lutidine Chloride Complexes, Tyler James Morin, Sarath Wanniarachchi, Chengeto Gwengo, Vitales Makura, Heidi M. Tatlock, Sergey Lindeman, Brian Bennett, Gary J. Long, Fernande Grandjean, and James R. Gardinier

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An In Vitro Spectroscopic Analysis to Determine the Chemical Composition of the Precipitate Formed by Mixing Sodium Hypochlorite and Chlorhexidine, James B. Nowicki and Daniel S. Sem

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Direct Patterning of a Cyclotriveratrylene Derivative for Directed Self-assembly of C60, Zachary R. Osner, Dorjderem Nyamjav, Richard C. Holz, and Daniel P. Becker

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Synthesis and Characterization of Fe(II) β-Diketonato Complexes with Relevance to Acetylacetone Dioxygenase: Insights into the Electronic Properties of the 3-Histidine Facial Triad, Heaweon Park, Jacob Baus, Sergey V. Lindeman, and Adam T. Fiedler

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Copper-Catalyzed Arylation of 1H-Perfluoroalkanes, Ilya Popov, Sergey V. Lindeman, and Olafs Daugulis

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Synthesis of Hydroxy- and Polyhydroxy-Substituted 1,3-Diaminocyclohexanes, Anobick Sar, Sergey Lindeman, and William Donaldson

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EVA-Layered Double Hydroxide (Nano)Composites: Mechanism of Fire Retardancy, Xiaolan Wang, Rajendra Rathore, Ponusa Songtipya, Maria del Mar Jimenez-Gasco, Evangelos Manias, and Charles A. Wilkie

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Preparation, Properties, and Reactivity of carbonylrhodium(I) Complexes of di(2-pyrazolylaryl)amido-pincer Ligands, Sarath Wanniarachchi, Brendan J. Liddle, Sergey V. Lindeman, and James R. Gardinier

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Using Sterics to Promote Reactivity in fac-Re(CO)3 Complexes of Some ‘Non-Innocent’ NNN-Pincer Ligands, Sarath Wanniarachchi, Brendan J Liddle, John Toussaint, Sergey Lindeman, Brian Bennett, and James R. Gardinier

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Recent Advances in the Synthetic and Mechanistic Aspects of the Ruthenium-catalyzed Carbon-heteroatom Bond Forming Reactions of Alkenes and Alkynes, Chae S. Yi

Submissions from 2010

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Thermal Degradation of High-Temperature Fluorinated Polyimide and its Carbon Fiber Composite, Andrea D. Adamczak, Adam A. Spriggs, Danielle M. Fitch, Walid Awad, Charles A. Wilkie, and Jaime C. Grunlan

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Investigation of the Thermal Degradation of Polyurea: The Effect of Ammonium Polyphosphate and Expandable Graphite, Walid Awad and Charles A. Wilkie

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Resin-modified Glass-ionomer Setting Reaction Competition, David W. Berzins, S. Abey, M. C. Costache, Charles A. Wilkie, and H. W. Roberts

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High-throughput Method for Estimating the Time to Sustained Ignition of Polystyrene-Clay Nanocomposites Based on Thermogravimetric Analysis, Marius C. Costache and Charles A. Wilkie

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Affinity capillary electrophoretic study of K+/Na+ selectivity of hexaarylbenzene-based polyaromatic receptor, Sille Ehala, Rajendra Rathore, Emanuel Makrlik, Petr Toman, and Václav Kašička

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Immobilization of the Aminopeptidase from Aeromonas proteolytica on Mg2+/Al3+ Layered Double Hydroxide Particles, Steven T. Frey, Stephanie L. Guilmet, Richard G. Egan III, Alyssa Bennett, Sarah R. Soltau, and Richard C. Holz

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Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C–H Bond Activation, Ruili Gao and Chae S. Yi

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X-ray Structure of mer-[Mo(CO)3(PPh3)(κ2-dppm)], Shishir Ghosh, Shariff E. Kabir, Faranza K. Camellia, Md. Kamal Hossain, Daniel T. Haworth, Sergey V. Lindeman, Tasneem A. Siddiquee, and Dennis W. Bennett

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The Rational Synthesis of Tetranuclear Heterometallic Butterfly Clusters: Reactions of [M2(CO)6(μ-pyS)2] (M = Re, Mn) with Group VIII Metal Carbonyls, Shishir Ghosh, Kamrun N. Khanam, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Graeme Hogarth, and Shariff E. Kabir

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Mixed-metal Cluster Synthesis: [Re(CO)3(μ-S2NC7H4)]2 as a Precursor for tri- and tetranuclear 2-mercaptobenzothiolato Capped Clusters, Shishir Ghosh, Kamrun N. Khanam, Md. Kamal Hossain, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Graeme Hogarth, and Shariff E. Kabir

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Inhibitors of Nα-acetyl-l-ornithine Deacetylase: Synthesis, Characterization and Analysis of their Inhibitory Potency, J. Hlavacek, J. Picha, V. Vanek, J. Jiracek, J. Slaninova, V. Fucik, M. Budesinsky, Danuta M. Gillner, and Richard C. Holz

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Isomerization as a Key Path to Molecular Products in the Gas-Phase Decomposition of Halons, Aimable Kalume, Lisa George, and Scott Reid

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Chelate-Assisted Oxidative Coupling Reaction of Arylamides and Unactivated Alkenes: Mechanistic Evidence for Vinyl C–H Bond Activation Promoted by an Electrophilic Ruthenium-Hydride Catalyst, Ki Hyeok Kwon, Do W. Lee, and Chae S. Yi

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Chain-Selective and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: New Insights on the Styrene Dimerization Mechanism, Do W. Lee and Chae S. Yi

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Tricarbonylrhenium(I) and Manganese(I) Complexes of 2-(pyrazolyl)-4-toluidine, Brendan J Liddle, Sarath Wanniarachchi, Sergey V. Lindeman, and James R. Gardinier

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Study on Intumescent Flame Retarded Polystyrene Composites with Improved Flame Retardancy, Hongdian Lu and Charles A. Wilkie

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Synergistic Effect of Carbon Nanotubes and Decabromodiphenyl Oxide/Sb2O3 in Improving the Flame Retardancy of Polystyrene, Hongdian Lu and Charles A. Wilkie

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Anion Exchange Kinetics of Nanodimensional Layered Metal Hydroxides: Use of Isoconversional Analysis, Stephen Majoni and Jeanne Hossenlopp

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The Effect of Boron-Containing Layered Hydroxy Salt (LHS) on the Thermal Stability and Degradation Kinetics of Poly (Methyl Methacrylate), Stephen Majoni, Shengpei Su, and Jeanne Hossenlopp

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Defining the Structural Consequences of Mechanism-Based Inactivation of Mammalian Cytochrome P450 2B4 Using Resonance Raman Spectroscopy, Piotr J. Mak, Haoming Zhang, Paul F. Hollenberg, and James R. Kincaid

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Breaking the Cycle: Impact of Sterically-Tailored Tetra(pyrazolyl)lutidines on the Self-Assembly of Silver(I) Complexes, Tyler James Morin, Andrew Merkel, Sergey V. Lindeman, and James R. Gardinier

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Structural Basis for Catalysis by the Mono- and Dimetalated Forms of the dapE-Encoded N-succinyl-L,L-Diaminopimelic Acid Desuccinylase, Boguslaw P. Nocek, Danuta Gillner, Yao Fan, Richard C. Holz, and Andzrej Joachimiak

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Direct Patterning of Silanized-Biomolecules on Semiconductor Surfaces, Dorjderem Nyamjav and Richard C. Holz

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Immobilization of Motile Bacterial Cells via Dip-pen Nanolithography, Dorjderem Nyamjav, Sergey Rozhok, and Richard C. Holz

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NMR Dynamics Investigation of Ligand-Induced Changes of Main and Side-Chain Arginine N-H’s in Human Phosphomevalonate Kinase, Andrew L. Olson, Sheng Cai, Timothy J. Herdendorf, Henry M. Miziorko, and Daniel S. Sem

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A Shortened Synthesis of Optically Pure Tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]Iron Leading to Improved Yield, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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Thermal Degradation Studies on PMMA–HET Acid Based Oligoesters Blends, Thangamani Rajkumar, Chinnaswamy Thangavel Vijayakumar, Palanichamy Sivasamy, Bojja Sreedhar, and Charles A. Wilkie

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Reactions of 1,1-Diiodo-3,4-benzocyclopentatellurane with Sulfur and Selenium Ligands: X-Ray Structure of a Dicationic Telluraheterocycle, [C8H8Te{S=C(Nme2)2}2][BF4]2, Martin D. Rudd, Nathan Edeler, Emily Ricks, and Sergey V. Lindeman

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De novo synthesis of polyhydroxyl aminocyclohexanes, Anobick Sar, Sergey Lindeman, and William Donaldson

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An In Vitro Spectroscopic Analysis to Determine Whether Para-Chloroaniline Is Produced from Mixing Sodium Hypochlorite and Chlorhexidine, John Thomas and Daniel S. Sem

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Synthesis of N-Succinyl-L,L-Diaminopimelic Acid Mimetics Via Selective Protection, V. Vanek, J. Picha, M. Budesinsky, M. Sanda, J. Jiracek, Richard C. Holz, and J. Hlavacek

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The Utility of Nanocomposites in Fire Retardancy, Linjiang Wang, Xuejun He, and Charles A. Wilkie

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A Comparison of the Fire Retardancy of Poly(Methyl Methacrylate) Using MMT, LDH and Kaolinite, Linjiang Wang, Xiangli Xie, Shengpei Shu, Jiangxiang Feng, and Charles A. Wilkie

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Chemical Switching Behaviour of Tricarbonylrhenium(I) Complexes of a New Redox Active ‘Pincer’ Ligand, Sarath Wanniarachchi, Brendan J Liddle, John Toussaint, Sergey Lindeman, Brian Bennett, and James R. Gardinier

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Infrared Spectroelectrochemical Reduction of Iron Porphyrin Complexes, Zhongcheng Wei and Michael D. Ryan

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Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C–H Bond Activation, Chae S. Yi and Do W. Lee

Submissions from 2009

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Material properties of nanoclay PVC composites, Walid Awad, Gunter Beyer, Daphne Benderly, Wouter L. Ijdo, Ponusa Songtipya, Maria del Mar Jimenez-Gasco, Evangelos Manias, and Charles A. Wilkie

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Development of Polyurea Nanocomposites with Improved Fire Retardancy, Walid Awad, Calistor Nyambo, Seogjun Kim, Robert J. Dinan, Jeff W. Fisher, and Charles A. Wilkie

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Linking Conformation Change to Hemoglobin Activation Via Chain-Selective Time-resolved Resonance Raman Spectroscopy on Protoheme/Mesoheme Hybrids, Gurusamy Balakrishnan, Mohammed Ibrahim, Piotr J. Mak, Jessica Hata, James R. Kincaid, and Thomas G. Spiro

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Subunit-Selective Interrogation of CO Recombination in Carbonmonoxy Hemoglobin by Isotope-Edited Time-Resolved Resonance Raman Spectroscopy, Gurusamy Balakrishnan, Xiaojie Zhao, Edyta Podstawska, Leonard M. Proniewicz, James R. Kincaid, and Thomas G. Spiro

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X-ray Structural Characterization of Charge Delocalization onto the Three Equivalent Benzenoid Rings in Hexamethoxytriptycene Cation Radical, Vincent J. Chebny, Tushar S. Navale, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor, Vincent J. Chebny, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis, William Donaldson and Subhabrata Chaudhury

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Discriminating Pulmonary Hypertension Caused by Monocrotaline Toxicity from Chronic Hypoxia by Near-Infrared Spectroscopy and Multivariate Methods of Analysis, Simon Duri, Robert C. Molthen, and Chieu D. Tran

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Investigations of 2-Thiazoline-2-thiol as a Ligand: Synthesis and X-ray Structures of [Mn2(CO)7(μ-NS2C3H4)2] and [Mn(CO)3(PPh3)(κ2-NS2C3H4)], Shishir Ghosh, Faruque Ahmed, Rafique Al-Mamun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, and Shariff E. Kabir

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Reactivity of phenyldi(2-thienyl)phosphine towards Group 7 Metal Carbonyls: Carbon–phosphorus Bond Activation, Shishir Ghosh, Alok K. Das, Noorjahan Begum, Daniel T. Haworth, Sergey Lindeman, James R. Gardinier, Tasneem A. Siddiquee, Dennis W. Bennett, Ebbe Nordlander, Graeme Hogarth, and Shariff E. Kabir

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Decarbonylation Reaction of [Os3(CO)10(μ-H)(μ-SN2C4H5)]: X-ray Structures of the Two Isomers of [Os3(CO)9(μ-H)(μ3-η2-SN2C4H5)], Shishir Ghosh, Shariff E. Kabir, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, and Dennis W. Bennett

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New Mixed-Metal Carbonyl Complexes Containing Bridging 2-Mercapto-1-methylimidazole Ligand, Shishir Ghosh, Shariff E. Kabir, Salina Pervin, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, and Herbert W. Roesky

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Tetranuclear Group 7/8 Mixed-Metal and Open Trinuclear Group 7 Metal Carbonyl Clusters Bearing Bridging 2-mercapto-1-methylimidazole Ligands, Shishir Ghosh, Shariff E. Kabir, Salina Pervin, Arun K. Raha, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Dennis W. Bennett, Tasneem Siddiquee, Luca Salassa, and Herbert W. Roesky

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Activation of Tri(2-Furyl)Phosphine at a Dirhenium Centre: Formation of Phosphido-Bridged Dirhenium Complexes, Shishir Ghosh, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, Graeme Hogarth, Ebbe Nordlander, and Shariff E. Kabir

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Inhibitors of Bacterial N-succinyl-L,L-diaminopimelic Acid Desuccinylase (DapE) and Demonstration of in vitro Antimicrobial Activity, Danuta Gillner, Nicola Armoush, Richard C. Holz, and Daniel P. Becker

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The dapE-encoded N-succinyl-l,l-diaminopimelic Acid Desuccinylase from Haemophilus influenzae Contains Two Active-site Histidine Residues, Danuta Gillner, David L. Bienvenue, Boguslaw P. Nocek, Andzrej Joachimiak, Vincentos Zachary, Brian Bennett, and Richard C. Holz

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Synthetic studies directed toward guianolides: an organoiron route to the 5,7,5 tricyclic ring system, Jayapal Reddy Gone, Nathaniel J Wallock, Sergey Lindeman, and William Donaldson

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Toward Charge-neutral ‘soft scorpionates’: Coordination Chemistry and Lewis Acid Promoted Isomerization of tris(1-organo-imidazol-2-ylthio)methanes, Chengeto Gwengo, Rosalice M. Silva, Mark D. Smith, Sergey V. Lindeman, and James R. Gardinier

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Effects of Hydroxy Double Salts and Related Nanodimensional-Layered Metal Hydroxides on Polymer Thermal Stability, Everson Kandare and Jeanne Hossenlopp

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Manipulating Self-Assembly in Silver(I) Complexes of 1,3-Di-N-pyrazolylorganyls, Brendan J. Liddle, Daniel Hall, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier

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A Versatile Synthesis of Electroactive Stilbenoprismands for Effective Binding of Metal Cations, Sergey V. Lindeman, Rajendra Rathore, and Paromita Debroy

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Structure - property relationships of new polystyrene nanocomposites prepared from initiator-containing layered double hydroxides of zinc aluminum and magnesium aluminum, Charles Manzi-Nshuti, Dan Chen, Shengpei Shu, and Charles A. Wilkie

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The Effects of Intralayer Metal Composition of Layered Double Hydroxides on Glass Transition, Dispersion, Thermal and Fire Properties of Their PMMA Nanocomposites, Charles Manzi-Nshuti, Dan Chen, Shengpei Su, and Charles A. Wilkie

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Comparative Study on the Flammability of Polyethylene Modified with Commercial Fire Retardants and a Zinc Aluminum Oleate Layered Double Hydroxide, Charles Manzi-Nshuti, Jeanne Hossenlopp, and Charles A. Wilkie

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Polymer Nanocomposites Using Zinc Aluminum and Magnesium Aluminum Oleate Layered Double Hydroxides: Effects of LDH Divalent Metals on Dispersion, Thermal, Mechanical and Fire Performance in Various Polymers, Charles Manzi-Nshuti, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, Jeanne Hossenlopp, and Charles Wilkie

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Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides: Effects of the polymeric compatibilizer and of composition on the thermal and fire properties of PP/LDH nanocomposites, Charles Manzi-Nshuti, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, Jeanne Hossenlopp, and Charles A. Wilkie

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The Role of the Trivalent metal in an LDH: Synthesis, Characterization and Fire Properties of Thermally Stable PMMA/LDH Systems, Charles Manzi-Nshuti, Dongyan Wang, Jeanne Hossenlopp, and Charles A. Wilkie

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Use of Layered Double Hydroxides as Polymer Fire-Retardant Additives: Advantages and Challenges, Charles Manzi-Nshuti, Liying Zhu, Calistor Nyambo, Linjiang Wang, Charles A. Wilkie, and Jeanne Hossenlopp

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13C-Methyl isocyanide as an NMR probe for cytochrome P450 active site, Christopher R McCullough, Phani Kumar Pullela, Sang-Choul Im, Lucy Waskell, and Daniel S. Sem

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Mutation of H63 and its Catalytic Affect on the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Brian Bennett, and Richard C. Holz

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Mutation of H63 and Its Catalytic Affect on the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Brian Bennett, and Richard C. Holz

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Analyzing the Binding of Co(II)-specific Inhibitors to the Methionyl Aminopeptidases from Escherichia coli and Pyrococcus furiosus, Sanghamitra Mitra, George Sheppard, Jieyi Wang, Brian Bennett, and Richard C. Holz

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Analyzing the Binding of Co(II)-specific Inhibitors to the Methionyl Aminopeptidases from Escherichia coli and Pyrococcus furiosus, Sanghamitra Mitra, George Sheppard, Jieyi Wang, Brian Bennett, and Richard C. Holz

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A Versatile Preparation of Geländer-Type p-Terphenyls from a Readily Available Diacetylenic Precursor, Matthew J. Modjewski, Sergey V. Lindeman, and Rajendra Rathore

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Isolation and X-ray Structural Characterization of a Dicationic Homotrimer of 2,3,6,7-tetramethoxy-9,10-dimethylanthracene cation radical, Matthew J. Modjewski, Ruchi Shukla, Sergey Lindeman, and Rajendra Rathore

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Molecular Motion and Performance Enhancement of BORAZAN Fluorescent Dyes, Tyler James Morin, Sergey Lindeman, and James R. Gardinier

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Octamethoxydibenzochrysene: Isolation and X-ray Crystallographic Characterization of a Twisted Polyaromatic Cation Radical, Tushar Navale, Linyi Zhai, Sergey V. Lindeman, and Rajendra Rathore

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Fire Retardancy in 2009, Gordon L. Nelson, Alexander B. Morgan, and Charles A. Wilkie

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Does organic modification of layered double hydroxides improve the fire performance of PMMA?, Calistor Nyambo, Dan Chen, Shengpei Shu, and Charles A. Wilkie

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Variation of benzyl anions in MgAl-layered double hydroxides: Fire and thermal properties in PMMA, Calistor Nyambo, Dan Chen, Shengpei Shu, and Charles A. Wilkie

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Thermal stability and flammability characteristics of ethylene vinyl acetate (EVA) composites blended with a phenyl phosphonate-intercalated layered double hydroxide (LDH), melamine polyphosphate and/or boric acid, Calistor Nyambo, Everson Kandare, and Charles A. Wilkie

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Will Layered Double Hydroxides Give Nanocomposites with Polar or Non-polar Polymers?, Calistor Nyambo, Dongyan Wang, and Charles A. Wilkie

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Layered double hydroxides intercalated with borate anions: Fire and thermal properties in ethylene vinyl acetate copolymer, Calistor Nyambo and Charles A. Wilkie