The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2008

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Formation of Bicyclic Pyrroles from the Catalytic Coupling Reaction of 2,5-disubstituted Pyrroles with Terminal Alkynes, Involving the Activation of Multiple C-H bonds, Chase S. Yi and Jie Zhang

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Chiral Ionic Liquids:  Synthesis, Properties, and Enantiomeric Recognition, Shaofang Yu, Sergey V. Lindeman, and Chieu D. Tran

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Polymerically Modified Layered Silicates: An Effective Route to Nanocomposites, Jinguo Zhang, Evangelos Manias, and Charles A. Wilkie

Submissions from 2007

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Chemistry and Biology of Streptogramin A Antibiotics, Fahim Ahmed and William Donaldson

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Practical Synthesis of Unsymmetrical Tetraarylethylenes and Their Application for the Preparation of [Triphenylethylene−Spacer−Triphenylethylene] Triads, Moloy Banerjee, Susanna J. Emond, Sergey V. Lindeman, and Rajendra Rathore

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Structural Characterization of Quaterphenyl Cation Radical:  X-ray Crystallographic Evidence of Quinoidal Charge Delocalization in Poly-p-phenylene Cation Radicals, Moloy Banerjee, Sergey V. Lindeman, and Rajendra Rathore

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The Crystal and Molecular Structure of a Trifluoroacetylacetonate Complex of Scandium, Sc(CH3COCHCOCF3)3, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and Sergey V. Lindeman

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Generation of molecular complexity from cyclooctatetraene: synthesis of a protected 2-(3′-carboxy-2′-benzoylcyclopentyl)glycine, Subhabrata Chaudhury, Sergey Lindeman, and William Donaldson

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Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations, Subhabrata Chaudhury, Shukun Li, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Revealing Nano-confinement in Degradation and Relaxation Studies of Two Structurally Different Polystyrene-Clay Systems, Kai Chen, Charles A. Wilkie, and Sergey Vyazovkin

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Enhanced Fire Retardancy of Vinyl Ester Resins by Combination of Additives, Grace Chigwada and Charles A. Wilkie

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The Influence of Carbon Nanotubes, Organically Modified Montmorillonites and Layered Double Hydroxides on the Thermal Degradation and Fire Retardancy of Polyethylene, Ethylene-Vinyl Acetate Copolymer and Polystyrene, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Giovanni Camino, Alberto Frache, Gunter Beyer, Rakesh K. Gupta, and Charles A. Wilkie

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Benzimidazolium Surfactants for Modification of Clays for Use with Styrenic Polymers, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Rakesh K. Gupta, and Charles A. Wilkie

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Hexabenzo[4.4.4]propellane:  A Helical Molecular Platform for the Construction of Electroactive Materials, Paromita Debroy, Sergey V. Lindeman, and Rajendra Rathore

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Preparation of Chiral Cholestanofluorene and Its Electron-Rich Derivatives for Isolation of a Stable Cation−Radical Salt, Paromita Debroy, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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The Voltammetric Study of the Reduction of Tetraalkylammonium Perchlorate by Fe(TPP)2-, Chathra Shirani De Silva and Michael D. Ryan

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A ‘Metallic Tape’ Stabilized by an Unprecedented μ522211-) Scorpionate Binding Mode, James R. Gardinier, Rosalice M. Silva, Chengeto Gwengo, and Sergey V. Lindeman

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Reactivity of [Re2(CO)8(MeCN)2] with Thiazoles: Hydrido Bridged Dirhenium Compounds Bearing Thiazoles in Different Coordination Modes, Shariff E. Kabir, Faruque Ahmed, Anamika Das, Mohammad R. Hassan, Daniel T. Haworth, Sergey V. Lindeman, G. M. Golzar Hossain, Tasneem Siddiquee, and Dennis W. Bennett

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P–C and C–H Bond Cleavages of dppm in the Thermal Reaction of [Ru3(CO)10(μ-dppm)] with Benzothiophene: X-ray structures of [Ru6(μ-CO)(CO)134-PhP(C6H4)PPh}(μ6-C)] and [Ru4(CO)932-PhPCH2PPh2)(μ4611-C6H4)(μ-H)], Shariff E. Kabir, Mohammad R. Hassan, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, and Dennis W. Bennett

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A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I), Brendan J. Liddle, Sergey V. Lindeman, Daniel L. Reger, and James R. Gardinier

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BORAZANs:  Tunable Fluorophores Based on 2-(Pyrazolyl)aniline Chelates of Diphenylboron, Brendan J. Liddle, Rosalice M. Silva, Tyler James Morin, Felipe P. Macedo, Ruchi Shukla, Sergey V. Lindeman, and James R. Gardinier

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Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle, Piotr J. Mak, Ilia G. Denisov, Doreen Victoria, Thomas M. Makris, Tianjing Deng, Stephen G. Sligar, and James R. Kincaid

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Ferrocene and Ferrocenium Modified Clays and Their Styrene and EVA Composites, Charles Manzi-Nshuti and Charles A. Wilkie

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Unraveling the Catalytic Mechanism of Nitrile Hydratases, Sanghamitra Mitra and Richard C. Holz

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Practical Issues and Future Trends in Polymer Nanocomposite Flammability Research, Alexander B. Morgan and Charles A. Wilkie

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13C NMR Analysis of Biologically Produced Pyrene Residues by Mycobacterium sp. KMS in the Presence of Humic Acid, J. Karl C. Nieman, Richard C. Holz, and Ronald C. Sims

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Conserved Amino Acids in Each Subunit of the Heteroligomeric tRNA m1A58 Mtase from Saccharomyces cerevisiae Contribute to tRNA Binding, Sarah G. Ozanick, Janusz M. Bujnicki, Daniel S. Sem, and James T. Anderson

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Synthesis of Cyclopropanes via Organoiron Methodology: Stereoselective Preparation of Bi(cyclopropyl)s, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of trans-Pt(Pet3)2(SePh)2, Martin D. Rudd and Sergey V. Lindeman

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Use of Factor Analysis in Multi‐Electron Spectroelectrochemistry, Michael D. Ryan and Robert L. Keesey

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Binding of an Acetonitrile Molecule Inside the Ethereal Cavity of a Hexaarylbenzene-Based Receptor via a Synergy of C–H⋯O/C–H⋯π Interactions, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Electron Transfer Prompted Ejection of a Tightly Bound K+ from the Ethereal Cavity of a Hexaarylbenzene-Based Receptor, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine Cpa, Tasneem A. Siddiquee, Julie Lukesh, Sergey Sergey Lindeman, and William A. Donaldson

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Cycloaddition Reactions of Phthalimide Substituted Cyclic Polyenes with Heteroatom Dienophiles, Stephen S. Templin, Nathaniel J. Wallock, Daniel T. Haworth, William A. Donaldson, Dennis W. Bennett, and Tasneem Siddiquee

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Mechanism of Rate-Limiting Motions in Enzyme Function, Eric D. Watt, Hiroko Shimada, Evgueni Kovriguine, and J. Patrick Loria

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Intercalation Compounds and Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 2006

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Synergistic Use of Compound Properties and Docking Scores in Neural Network Modeling of CYP2D6 Binding: Predicting Affinity and Conformational Sampling, Peter S. Bazeley, Sridevi Prithivi, Craig Struble, Richard J. Povinelli, and Daniel S. Sem

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Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C42H54O5• CH3CN, Dennis W. Bennett, Tasneem A. Siddiquee, Daniel T. Haworth, Subhabrata Chaudhury, and William Donaldson

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Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones, Subhabrata Chaudhury and William Donaldson

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Synthetic studies directed toward the proposed structure for heteroscyphic acid A, Subhabrata Chaudhury, Shukun Li, and William Donaldson

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Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene, Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, and Rajendra Rathore

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Styrenic Nanocomposites Prepared using a Novel Biphenyl-Containing Clay, Grace Chigwada, Dongyan Wang, David D. Jiang, and Charles A. Wilkie

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Polystyrene Nanocomposites Based on Quinolinium and Pyridinium Surfactants, Grace Chigwada, Dongyan Wang, and Charles A. Wilkie

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Preparation and Characterization of Poly(Ethylene Terephtalate)/Clay Nanocomposites by Melt Blending using Thermally Stable Surfactants, Marius Cristian Costache, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie

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Fire Retardancy of Polyureas, Marius Cristian Costache, Eric M. Kanugh, Charles A. Wilkie, and Usman Sorathia

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The Thermal Degradation of Poly(methyl methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Marius C. Costache, Dongyan Wang, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie

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The High-Resolution Structures of the Neutral and the Low pH Crystals of Aminopeptidase from Aeromonas proteolytica, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Gregory A. Petsko, Dagmar Ringe, and Richard C. Holz

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The Proteomics of N-terminal Methionine Cleavage, Frédéric Frottin, Aude Martinez, Philippe Peynot, Sanghamitra Mitra, Richard C. Holz, Carmela Giglione, and Thierry Meinnel

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Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS), JIanwei Hao, Menachem Lewin, Charles A. Wilkie, and Jiangqi Wang

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Applications of Acoustic Wave Devices for Sensing in Liquid Environments, Jeanne Hossenlopp

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Nanostructured Layered Copper Hydroxy Dodecyl Sulfate: A Potential Fire Retardant for Poly(vinyl Ester) (PVE), Everson Kandare, Grace Chigwada, Dongyan Wang, Charles A. Wilkie, and Jeanne Hossenlopp

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Probing Synergism, Antagonism, and Additive Effects in Poly(vinyl Ester) (PVE) Composites with Fire Retardants, Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Thermal Stability and Degradation Kinetics of Poly(methyl Methacrylate)/Layered Copper Hydroxy Methacrylate Composites, Everson Kandare, Hongmei Deng, Dongyan Wang, and Jeanne Hossenlopp

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Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts, Everson Kandare and Jeanne Hossenlopp

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NMR Studies of Escherichia Coli Acyl Carrier Protein: Dynamic and Structural Differences of the Apo- and Holo-forms, Yangmee Kim, Evgueni Kovriguine, and Ziad Eletr

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Faithful Estimation of Dynamics Parameters from CPMG Relaxation Dispersion Measurements, Evgueni Kovriguine, James G. Kempf, Michael J. Grey, and J. Patrick Loria

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Characterization of the Transition State of Functional Enzyme Dynamics, Evgueni Kovriguine and J. Patrick Loria

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Enzyme Dynamics Along the Reaction Coordinate: Critical Role of a Conserved Residue, Evgueni Kovriguine and J. Patrick Loria

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Nanocomposites at Elevated Temperatures: Migration and Structural Changes, Menachem Lewin, E. M. Pearce, Kelle Levon, Abraham Mey-Marom, Mauro Zammarano, Charles A. Wilkie, and Bok Nam Jang

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A New Colorimetric Assay for Methionyl Aminopeptidases: Examination of the Binding of a New Class of Pseudopeptide Analog Inhibitors, Sanghamitra Mitra, Anna M. Dygas-Holz, Jiri Jiracek, Miroslava Zertova, Lenka Zakova, and Richard C. Holz

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Attachment of Motile Bacterial Cells to Prealigned Holed Microarrays, Sergey Rozhok, Zhifang Fan, Dorjderem Nyamjav, Chang Liu, Chad A. Mirkin, and Richard C. Holz

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The Redox Couple of the Cytochrome c Cyanide Complex: The Contribution of Heme Iron Ligation to the Structural Stability, Chemical Reactivity, and Physiological Behavior of Horse Cytochrome c, Abel Schejter, Michael D. Ryan, Erica R. Blizzard, Chongyao Zhang, Emanuel Margoliash, and Benjamin A. Feinberg

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A Practical Synthesis of Bridged Diarylacetylenes, Ruchi Shukla, Daniel M. Brody, Sergey V. Lindeman, and Rajendra Rathore

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A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Janus Scorpionates:  Supramolecular Tectons for the Directed Assembly of Hard−Soft Alkali Metallopolymer Chains, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier

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Ligand-Promoted Solvent-Dependent Ionization and Conformational Equilibria of Re(CO)3Br[CH2(S-tim)2] (tim = 1-methylthioimidazolyl). Crystal Structures of Re(CO)3Br[CH2(S-tim)2] and {Re(CO)3(CH3CN)[CH2(S-tim)2]}(PF6), Rosalice M. Silva, Brendan J. Liddle, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier

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Novel Potentiometric and Optical Silver Ion-selective Sensors with Subnanomolar Detection Limits, Zsófia Szigeti, Adam Malon, Tamás Vigassy, Viktor Csokai, Alajos Grün, Katarzyna Wygladacz, Nan Ye, Chao Xu, Vincent J. Chebny, István Bitter, Rajendra Rathore, Eric Bakker, and Ernö Pretsch

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TGA analysis of γ-Irradiated Linear Low Density Polyethylene, Adams Tidjani and Charles A. Wilkie

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation and Rearrangement of Divinylcyclopropanes - Studies Directed toward the Synthesis­ of Hydroazulenes, Nathaniel J Wallock, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Fire Properties of Polymer Nanocomposites, Charles A. Wilkie

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High-Throughput Techniques for the Evaluation of Fire Retardancy, Charles A. Wilkie, Grace Chigwada, Jeffery W. Gilman Sr., and Richard E. Lyon

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A Review of Recent Work in the Fire Retardancy of Nanocomposites, Charles A. Wilkie, Xiaoxia Zheng, Grace Chigwada, Marius C. Costache, Bok Nam Jang, and Jinguo Zhang

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Highly Cooperative Tetrametallic Ruthenium-μ-Oxo-μ-Hydroxo Catalyst for the Alcohol Oxidation Reaction, Chae S. Yi, Tonya N. Zeczycki, and Ilia A. Guzei

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Controlled Silylation of Montmorillonite and its Polyethylene Nanocomposites, Jinguo Zhang, Rakesh K. Gupta, and Charles A. Wilkie

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Styrenic Polymer Nanocomposites Based on an Oligomerically-Modified Clay with High Inorganic Content, Jinguo Zhang, David D. Jiang, Dongyan Wang, and Charles A. Wilkie

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Fire properties of styrenic polymer–clay nanocomposites based on an oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Polyethylene and polypropylene nanocomposites based on a three component oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Thermal and Flame Properties of Polyethylene and Polypropylene Nanocomposites Based on an Oligomerically–Modified Clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Fire Retardancy of Polypropylene-Metal Hydroxide Nanocomposites, Jinguo Zhang and Charles A. Wilkie

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Polyethylene and Polypropylene Nanocomposites Based on Polymerically - Modified Clay Containing Alkylstyrene Units, Jinguo Zhang and Charles A. Wilkie

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Flammability of styrenic polymer clay nanocomposites based on a methyl methacrylate oligomerically-modified clay, Xiaoxia Zheng, David D. Jiang, Dongyan Wang, and Charles A. Wilkie

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Polystyrene nanocomposites based on an oligomerically-modified clay containing maleic anhydride, Xiaoxia Zheng, David D. Jiang, and Charles A. Wilkie

Submissions from 2005

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Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics, Fahim Ahmed, Yeyu Cao, and William Donaldson

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Kinetic, Spectroscopic, and X-ray Crystallographic Characterization of the Functional E151H Aminopeptidase from Aeromonas proteolytica, Krzysztof P. Bzymek, Aaron Moulin, Sabina I. Swierczek, Dagmar Ringe, Gregory A. Petsko, Brian Bennett, and Richard C. Holz

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Fire Retardancy of Vinyl Ester Nanocomposites: Synergy with Phosphorus-Based Fire Retardants, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles A. Wilkie

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Synergy Between Nanocomposite Formation and Low Levels of Bromine on Fire Retardancy in Polystyrenes, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles A. Wilkie

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Fire Retardancy of Polystyrene Nanocomposites Using Naphthenate-Containing Clays, Grace Chigwada, David D. Jiang, and Charles A. Wilkie

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Polystyrene Nanocomposites based on Carbazole-Containing Surfactants, Grace Chigwada, David D. Jiang, and Charles A. Wilkie

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EPR and X-ray Crystallographic Characterization of the Product-Bound Form of the MnII-Loaded Methionyl Aminopeptidase from Pyrococcus furiosus, Alicja J. Copik, Boguslaw P. Nocek, Sabina I. Swierczek, Shane Ruebush, Se Bok Jang, Lu Meng, Ventris M. D'Souza, John W. Peters, Brian Bennett, and Richard C. Holz

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Thermal Degradation of Ethylene-Vinyl Acetate Copolymer Nanocomposites, Marius C. Costache, David D. Jiang, and Charles A. Wilkie

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Isolation, X-ray Structures, and Electronic Spectra of Reactive Intermediates in Friedel−Crafts Acylations, M. G. Davlieva, Sergey V. Lindeman, I. S. Neretin, and Jay K. Kochi

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Combined X-ray diffraction and diffuse reflectance analysis of nanocrystalline mixed Sn(II) and Sn(IV) Oxide Powders, Hongmei Deng and Jeanne Hossenlopp

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Characterization of the Active Site and Insight into the Binding Mode of the Anti-angiogenesis Agent Fumagillin to the Manganese(II)-Loaded Methionyl Aminopeptidase from Escherichia coli, Ventris M. D'Souza, Robert S. Brown, Brian Bennett, and Richard C. Holz

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The Relationship Between Thermal Degradation Behavior of Polymer and the Fire Retardancy of Polymer/Clay Nanocomposites, Bok Nam Jang, Marius C. Costache, and Charles A. Wilkie

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The Relationship Between the Solubility Parameter of Polymers and the Clay-Dispersion in Polymer/Clay Nanocomposites and the Role of the Surfactant, Bok Nam Jang, Dongyan Wang, and Charles A. Wilkie

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The Effect of Clay on the Thermal Degradation of Polyamide 6 in Polyamide 6/Clay Nanocomposites, Bok Nam Jang and Charles A. Wilkie

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The Effects of Clay on the Thermal Degradation Behavior of Poly(Styrene-co-Acrylonitirile), Bok Nam Jang and Charles A. Wilkie

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The Effects Of Triphenylphosphate and Recorcinolbis(Diphenylphosphate) on the Thermal Degradation Of Polycarbonate in Air, Bok Nam Jang and Charles A. Wilkie

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The Thermal degradation of Bisphenol A Polycarbonate in Air, Bok Nam Jang and Charles A. Wilkie

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The Thermal Degradation of Polystyrene Nanocomposites, Bok Nam Jang and Charles A. Wilkie