The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2007

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Unraveling the Catalytic Mechanism of Nitrile Hydratases, Sanghamitra Mitra and Richard C. Holz

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Practical Issues and Future Trends in Polymer Nanocomposite Flammability Research, Alexander B. Morgan and Charles A. Wilkie

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X-ray Crystallographic Characterization of the Co(II)-substituted Tris-bound Form of the Aminopeptidase from Aeromonas proteolytica, Petra Munih, Aaron Moulin, Carin Stamper, Brian Bennett, Dagmar Ringe, Gregory A. Petsko, and Richard C. Holz

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13C NMR Analysis of Biologically Produced Pyrene Residues by Mycobacterium sp. KMS in the Presence of Humic Acid, J. Karl C. Nieman, Richard C. Holz, and Ronald C. Sims

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Conserved Amino Acids in Each Subunit of the Heteroligomeric tRNA m1A58 Mtase from Saccharomyces cerevisiae Contribute to tRNA Binding, Sarah G. Ozanick, Janusz M. Bujnicki, Daniel S. Sem, and James T. Anderson

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Synthesis of Cyclopropanes via Organoiron Methodology: Stereoselective Preparation of Bi(cyclopropyl)s, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of trans-Pt(Pet3)2(SePh)2, Martin D. Rudd and Sergey V. Lindeman

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Use of Factor Analysis in Multi‐Electron Spectroelectrochemistry, Michael D. Ryan and Robert L. Keesey

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Binding of an Acetonitrile Molecule Inside the Ethereal Cavity of a Hexaarylbenzene-Based Receptor via a Synergy of C–H⋯O/C–H⋯π Interactions, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Electron Transfer Prompted Ejection of a Tightly Bound K+ from the Ethereal Cavity of a Hexaarylbenzene-Based Receptor, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine Cpa, Tasneem A. Siddiquee, Julie Lukesh, Sergey Sergey Lindeman, and William A. Donaldson

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Cycloaddition Reactions of Phthalimide Substituted Cyclic Polyenes with Heteroatom Dienophiles, Stephen S. Templin, Nathaniel J. Wallock, Daniel T. Haworth, William A. Donaldson, Dennis W. Bennett, and Tasneem Siddiquee

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Mechanism of Rate-Limiting Motions in Enzyme Function, Eric D. Watt, Hiroko Shimada, Evgueni Kovriguine, and J. Patrick Loria

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Intercalation Compounds and Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 2006

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Synergistic Use of Compound Properties and Docking Scores in Neural Network Modeling of CYP2D6 Binding: Predicting Affinity and Conformational Sampling, Peter S. Bazeley, Sridevi Prithivi, Craig Struble, Richard J. Povinelli, and Daniel S. Sem

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Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C42H54O5• CH3CN, Dennis W. Bennett, Tasneem A. Siddiquee, Daniel T. Haworth, Subhabrata Chaudhury, and William Donaldson

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Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones, Subhabrata Chaudhury and William Donaldson

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Synthetic studies directed toward the proposed structure for heteroscyphic acid A, Subhabrata Chaudhury, Shukun Li, and William Donaldson

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Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene, Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, and Rajendra Rathore

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Styrenic Nanocomposites Prepared using a Novel Biphenyl-Containing Clay, Grace Chigwada, Dongyan Wang, David D. Jiang, and Charles A. Wilkie

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Polystyrene Nanocomposites Based on Quinolinium and Pyridinium Surfactants, Grace Chigwada, Dongyan Wang, and Charles A. Wilkie

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Preparation and Characterization of Poly(Ethylene Terephtalate)/Clay Nanocomposites by Melt Blending using Thermally Stable Surfactants, Marius Cristian Costache, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie

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Fire Retardancy of Polyureas, Marius Cristian Costache, Eric M. Kanugh, Charles A. Wilkie, and Usman Sorathia

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The Thermal Degradation of Poly(methyl methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Marius C. Costache, Dongyan Wang, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie

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Kinetic and Spectroscopic Characterization of the E134A- and E134D-altered dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase from Haemophilus influenzae, Ryan S. Davis, David L. Bienvenue, Sabina I. Swierczek, Danuta M. Gilner, Lakshman Rajagopal, Brian Bennett, and Richard C. Holz

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The High-Resolution Structures of the Neutral and the Low pH Crystals of Aminopeptidase from Aeromonas proteolytica, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Gregory A. Petsko, Dagmar Ringe, and Richard C. Holz

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The Proteomics of N-terminal Methionine Cleavage, Frédéric Frottin, Aude Martinez, Philippe Peynot, Sanghamitra Mitra, Richard C. Holz, Carmela Giglione, and Thierry Meinnel

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Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS), JIanwei Hao, Menachem Lewin, Charles A. Wilkie, and Jiangqi Wang

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Applications of Acoustic Wave Devices for Sensing in Liquid Environments, Jeanne Hossenlopp

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Nanostructured Layered Copper Hydroxy Dodecyl Sulfate: A Potential Fire Retardant for Poly(vinyl Ester) (PVE), Everson Kandare, Grace Chigwada, Dongyan Wang, Charles A. Wilkie, and Jeanne Hossenlopp

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Probing Synergism, Antagonism, and Additive Effects in Poly(vinyl Ester) (PVE) Composites with Fire Retardants, Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Thermal Stability and Degradation Kinetics of Poly(methyl Methacrylate)/Layered Copper Hydroxy Methacrylate Composites, Everson Kandare, Hongmei Deng, Dongyan Wang, and Jeanne Hossenlopp

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Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts, Everson Kandare and Jeanne Hossenlopp

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NMR Studies of Escherichia Coli Acyl Carrier Protein: Dynamic and Structural Differences of the Apo- and Holo-forms, Yangmee Kim, Evgueni Kovriguine, and Ziad Eletr

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Faithful Estimation of Dynamics Parameters from CPMG Relaxation Dispersion Measurements, Evgueni Kovriguine, James G. Kempf, Michael J. Grey, and J. Patrick Loria

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Characterization of the Transition State of Functional Enzyme Dynamics, Evgueni Kovriguine and J. Patrick Loria

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Enzyme Dynamics Along the Reaction Coordinate: Critical Role of a Conserved Residue, Evgueni Kovriguine and J. Patrick Loria

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Nanocomposites at Elevated Temperatures: Migration and Structural Changes, Menachem Lewin, E. M. Pearce, Kelle Levon, Abraham Mey-Marom, Mauro Zammarano, Charles A. Wilkie, and Bok Nam Jang

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A New Colorimetric Assay for Methionyl Aminopeptidases: Examination of the Binding of a New Class of Pseudopeptide Analog Inhibitors, Sanghamitra Mitra, Anna M. Dygas-Holz, Jiri Jiracek, Miroslava Zertova, Lenka Zakova, and Richard C. Holz

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Attachment of Motile Bacterial Cells to Prealigned Holed Microarrays, Sergey Rozhok, Zhifang Fan, Dorjderem Nyamjav, Chang Liu, Chad A. Mirkin, and Richard C. Holz

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The Redox Couple of the Cytochrome c Cyanide Complex: The Contribution of Heme Iron Ligation to the Structural Stability, Chemical Reactivity, and Physiological Behavior of Horse Cytochrome c, Abel Schejter, Michael D. Ryan, Erica R. Blizzard, Chongyao Zhang, Emanuel Margoliash, and Benjamin A. Feinberg

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A Practical Synthesis of Bridged Diarylacetylenes, Ruchi Shukla, Daniel M. Brody, Sergey V. Lindeman, and Rajendra Rathore

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A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore

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Janus Scorpionates:  Supramolecular Tectons for the Directed Assembly of Hard−Soft Alkali Metallopolymer Chains, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier

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Ligand-Promoted Solvent-Dependent Ionization and Conformational Equilibria of Re(CO)3Br[CH2(S-tim)2] (tim = 1-methylthioimidazolyl). Crystal Structures of Re(CO)3Br[CH2(S-tim)2] and {Re(CO)3(CH3CN)[CH2(S-tim)2]}(PF6), Rosalice M. Silva, Brendan J. Liddle, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier

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Novel Potentiometric and Optical Silver Ion-selective Sensors with Subnanomolar Detection Limits, Zsófia Szigeti, Adam Malon, Tamás Vigassy, Viktor Csokai, Alajos Grün, Katarzyna Wygladacz, Nan Ye, Chao Xu, Vincent J. Chebny, István Bitter, Rajendra Rathore, Eric Bakker, and Ernö Pretsch

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TGA analysis of γ-Irradiated Linear Low Density Polyethylene, Adams Tidjani and Charles A. Wilkie

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation and Rearrangement of Divinylcyclopropanes - Studies Directed toward the Synthesis­ of Hydroazulenes, Nathaniel J Wallock, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Fire Properties of Polymer Nanocomposites, Charles A. Wilkie

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High-Throughput Techniques for the Evaluation of Fire Retardancy, Charles A. Wilkie, Grace Chigwada, Jeffery W. Gilman Sr., and Richard E. Lyon

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A Review of Recent Work in the Fire Retardancy of Nanocomposites, Charles A. Wilkie, Xiaoxia Zheng, Grace Chigwada, Marius C. Costache, Bok Nam Jang, and Jinguo Zhang

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Highly Cooperative Tetrametallic Ruthenium-μ-Oxo-μ-Hydroxo Catalyst for the Alcohol Oxidation Reaction, Chae S. Yi, Tonya N. Zeczycki, and Ilia A. Guzei

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Controlled Silylation of Montmorillonite and its Polyethylene Nanocomposites, Jinguo Zhang, Rakesh K. Gupta, and Charles A. Wilkie

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Styrenic Polymer Nanocomposites Based on an Oligomerically-Modified Clay with High Inorganic Content, Jinguo Zhang, David D. Jiang, Dongyan Wang, and Charles A. Wilkie

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Fire properties of styrenic polymer–clay nanocomposites based on an oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Polyethylene and polypropylene nanocomposites based on a three component oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Thermal and Flame Properties of Polyethylene and Polypropylene Nanocomposites Based on an Oligomerically–Modified Clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie

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Fire Retardancy of Polypropylene-Metal Hydroxide Nanocomposites, Jinguo Zhang and Charles A. Wilkie

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Polyethylene and Polypropylene Nanocomposites Based on Polymerically - Modified Clay Containing Alkylstyrene Units, Jinguo Zhang and Charles A. Wilkie

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Flammability of styrenic polymer clay nanocomposites based on a methyl methacrylate oligomerically-modified clay, Xiaoxia Zheng, David D. Jiang, Dongyan Wang, and Charles A. Wilkie

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Polystyrene nanocomposites based on an oligomerically-modified clay containing maleic anhydride, Xiaoxia Zheng, David D. Jiang, and Charles A. Wilkie

Submissions from 2005

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Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics, Fahim Ahmed, Yeyu Cao, and William Donaldson

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Kinetic, Spectroscopic, and X-ray Crystallographic Characterization of the Functional E151H Aminopeptidase from Aeromonas proteolytica, Krzysztof P. Bzymek, Aaron Moulin, Sabina I. Swierczek, Dagmar Ringe, Gregory A. Petsko, Brian Bennett, and Richard C. Holz

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Spectroscopic and Thermodynamic Characterization of the E151D and E151A Altered Leucine Aminopeptidases from Aeromonas proteolytica, Krzysztof P. Bzymek, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz

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Fire Retardancy of Vinyl Ester Nanocomposites: Synergy with Phosphorus-Based Fire Retardants, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles A. Wilkie

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Synergy Between Nanocomposite Formation and Low Levels of Bromine on Fire Retardancy in Polystyrenes, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles A. Wilkie

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Fire Retardancy of Polystyrene Nanocomposites Using Naphthenate-Containing Clays, Grace Chigwada, David D. Jiang, and Charles A. Wilkie

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Polystyrene Nanocomposites based on Carbazole-Containing Surfactants, Grace Chigwada, David D. Jiang, and Charles A. Wilkie

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EPR and X-ray Crystallographic Characterization of the Product-Bound Form of the MnII-Loaded Methionyl Aminopeptidase from Pyrococcus furiosus, Alicja J. Copik, Boguslaw P. Nocek, Sabina I. Swierczek, Shane Ruebush, Se Bok Jang, Lu Meng, Ventris M. D'Souza, John W. Peters, Brian Bennett, and Richard C. Holz

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Thermal Degradation of Ethylene-Vinyl Acetate Copolymer Nanocomposites, Marius C. Costache, David D. Jiang, and Charles A. Wilkie

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Isolation, X-ray Structures, and Electronic Spectra of Reactive Intermediates in Friedel−Crafts Acylations, M. G. Davlieva, Sergey V. Lindeman, I. S. Neretin, and Jay K. Kochi

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Combined X-ray diffraction and diffuse reflectance analysis of nanocrystalline mixed Sn(II) and Sn(IV) Oxide Powders, Hongmei Deng and Jeanne Hossenlopp

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Characterization of the Active Site and Insight into the Binding Mode of the Anti-angiogenesis Agent Fumagillin to the Manganese(II)-Loaded Methionyl Aminopeptidase from Escherichia coli, Ventris M. D'Souza, Robert S. Brown, Brian Bennett, and Richard C. Holz

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The Relationship Between Thermal Degradation Behavior of Polymer and the Fire Retardancy of Polymer/Clay Nanocomposites, Bok Nam Jang, Marius C. Costache, and Charles A. Wilkie

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The Relationship Between the Solubility Parameter of Polymers and the Clay-Dispersion in Polymer/Clay Nanocomposites and the Role of the Surfactant, Bok Nam Jang, Dongyan Wang, and Charles A. Wilkie

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The Effect of Clay on the Thermal Degradation of Polyamide 6 in Polyamide 6/Clay Nanocomposites, Bok Nam Jang and Charles A. Wilkie

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The Effects of Clay on the Thermal Degradation Behavior of Poly(Styrene-co-Acrylonitirile), Bok Nam Jang and Charles A. Wilkie

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The Effects Of Triphenylphosphate and Recorcinolbis(Diphenylphosphate) on the Thermal Degradation Of Polycarbonate in Air, Bok Nam Jang and Charles A. Wilkie

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The Thermal degradation of Bisphenol A Polycarbonate in Air, Bok Nam Jang and Charles A. Wilkie

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The Thermal Degradation of Polystyrene Nanocomposites, Bok Nam Jang and Charles A. Wilkie

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Effects of Surfactants on the Thermal and Fire Properties of Poly(Methyl Methacrylate)/Clay Nanocomposites, Panchatapa Jash and Charles A. Wilkie

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ATR-FTIR Spectroscopic Analysis of Sorption of Aqueous Analytes into Polymer Coatings Used with Guided SH-SAW Sensors, Yolanda K. Jones, Zhonghui Li, Michael M. Johnson, Fabien Josse, and Jeanne Hossenlopp

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Hydroxy double salt anion exchange kinetics: effects of precursor structure and anion size, Everson Kandare and Jeanne Hossenlopp

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Isolation and X-ray Structures of Labile Benzoic- and Acetic-Acidium Carbocations, Sergey V. Lindeman, I. S. Neretin, M. G. Davlieva, and Jay K. Kochi

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Analysis of Liquid-Phase Chemical Detection Using Guided Shear Horizontal-Surface Acoustic Wave Sensors, Zhonghui Li, Yolanda Jones, Jeanne M. Hossenlopp, Richard Cernosek, and Fabien Josse

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“Separated” versus “Contact” Ion-Pair Structures in Solution from Their Crystalline States:  Dynamic Effects on Dinitrobenzenide as a Mixed-Valence Anion, Jian-Ming Lü, Sergiy V. Rosokha, Sergey V. Lindeman, Ivan S. Neretin, and Jay K. Kochi

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A short synthesis of the common dihydropyran segment of the antifungal agents ambruticin and jerangolid A, Julie Lukesh and William Donaldson

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Synthesis of cyclopropanes via organoiron methodology: preparation of the C9–C16 alkenylcyclopropane segment of ambruticin, Julie Lukesh and William Donaldson

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argE-Encoded N-Acetyl-l-Ornithine Deacetylase from Escherichia coli Contains a Dinuclear Metalloactive Site, Wade C. McGregor, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz

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Fire Retardancy in 2005, Gordon L. Nelson and Charles A. Wilkie

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Electrochemical Attachment of Motile Bacterial Cells to Gold, Sergey Rozhok and Richard C. Holz

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Methods for Fabricating Microarrays of Motile Bacteria, Sergey Rozhok, Clifton K. -F. Shen, Pey-Lih H. Littler, Zhifang Fan, Chang Liu, Chad A. Mirkin, and Richard C. Holz

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Polystyrenes with macro-intercalated organoclay. Part I: Compounding and Characterization, Maryam Sepehr, Leszek A. Utracki, Xiaoxia Zheng, and Charles A. Wilkie

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Polystyrenes with macro-intercalated organoclay. Part II: Rheology and Mechanical Performance, Maryam Sepehr, Leszek A. Utracki, Xiaoxia Zheng, and Charles A. Wilkie

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Molecular Discrimination of Type-I over Type-II Methionyl Aminopeptidases, Krzysztof Swierczek, Alicja J. Copik, Sabina I. Swierczek, and Richard C. Holz

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Expandable Graphite/Polyamide-6 Nanocomposites, Fawn Marie Uhl, Qiang Yao, Hiroyoshi Nakajima, Evangelos Manias, and Charles A. Wilkie

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Formation of nanocomposites of Styrene and its Copolymers using Graphite as the Nanomaterial, Fawn Marie Uhl, Qiang Yao, and Charles A. Wilkie

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation and Rearrangement of Divinylcyclopropanes, Nathaniel J. Wallock and William A. Donaldson

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Cone calorimetric and Thermogravimetric Analysis Evaluation of Halogen-Containing Polymer nanocomposites, Dongyan Wang, Kandice Echols, and Charles A. Wilkie

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Fire Retardancy of Polystyrene - Hectorite Nanocomposites, Dongyan Wang, Bok Nam Jang, Shengpei Su, Jinguo Zhang, Xiaoxia Zheng, Grace Chigwada, David D. Jiang, and Charles A. Wilkie