The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.
Submissions from 2008
Defining Resonance Raman Spectral Responses to Substrate Binding by Cytochrome P450 from Pseudomonas putida, Piotr J. Mak, Daniel Kaluka, Munyaradzi Edith Manyumwa, Haiqing Zhang, Tianjing Deng, and James R. Kincaid
Resonance Raman Spectroscopic Studies of Hydroperoxo Derivatives of Cobalt-substituted Myoglobin, Piotr J. Mak and James R. Kincaid
Fire Retardancy of Melamine and Zinc Aluminum Layered Double Hydroxide in Poly(methyl Methacrylate), Charles Manzi-Nshuti, Jeanne Hossenlopp, and Charles Wilkie
Aluminum-containing Layered Double Hydroxides: the Thermal, Mechanical, and Fire Properties of (Nano)composites of Poly(methyl Methacrylate), Charles Manzi-Nshuti, Dongyan Wang, Jeanne Hossenlopp, and Charles A. Wilkie
Analyzing the Catalytic Role of Asp97 in the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Kathleen M. Job, Lu Meng, Brian Bennett, and Richard C. Holz
First-Row Transition-Metal Complexes of a New Pentadentate Ligand, α,α,α′,α′-Tetra(pyrazolyl)lutidine, Tyler James Morin, Brian Bennett, Sergey V. Lindeman, and James R. Gardinier
Flame-retarded Polystyrene: Investigating Chemical Interactions between Ammonium Polyphosphate and MgAl Layered Double Hydroxide, Calistor Nyambo, Everson Kandare, Dongyan Wang, and Charles A. Wilkie
Effect of MgAl-layered double hydroxide exchanged with linear alkyl carboxylates on fire-retardancy of PMMA and PS, Calistor Nyambo, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, and Charles A. Wilkie
Global Conformational Dynamics in Ras, Casey O'Connor and Evgenii L. Kovrigin
Reactivity of (2-alkenyl-3-pentene-1,5-diyl)iron complexes: preparation of functionalized vinylcyclopropanes and cycloheptadienes, Rajesh K. Pandey, Lizhu Wang, Nathaniel J Wallock, Sergey V. Lindeman, and William A. Donaldson
HET acid based oligoesters – TGA/FTIR studies, Thangamani Rajkumar, Chinnaswamy Thangavel Vijayakumar, Palanichamy Sivasamy, and Charles A. Wilkie
Analyzing the Catalytic Mechanism of the Fe-Type Nitrile Hydratase from Comamonas testosteroni Ni1, Saroja Rao and Richard C. Holz
Bis[(dimethyl-λ4-sulfanylidene)oxonium] hexabromidotellurate(IV) dimethyl sulfoxide disolvate, Martin D. Rudd, Gregory Kokke, and Sergey V. Lindeman
Resonance Raman Interrogation of the Consequences of Heme Rotational Disorder in Myoglobin and its Ligated Derivatives, Freeborn Rwere, Piotr J. Mak, and James R. Kincaid
Synthesis, Electronic Properties, and X-ray Structural Characterization of Tetrarylbenzo[1,2-b:4,5-b′]difuran Cation Radicals, Ruchi Shukla, Shriya Wadumethrige, Sergey V. Lindeman, and Rajendra Rathore
A Second-Generation Janus Scorpionate Ligand: Controlling Coordination Modes in Iron(II) Complexes by Steric Modulation, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, Gary J. Long, Fernande Grandjean, and James R. Gardinier
Kinetic and Spectroscopic Analysis of the Catalytic Role of H79 in the Methionine Aminopeptidase from Escherichia coli, Sarah J. Watterson, Sanghamitra Mitra, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz
Nanocomposites I. Current Developments in Nanocomposites as Novel Fire Retardants, Charles A. Wilkie and Alexander B. Morgan
Kinetic, Spectroscopic, and X-Ray Crystallographic Evidence for the Cooperative Mechanism of the Hydration of Nitriles Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo Complex, Chae S. Yi, Tonya N. Zeczycki, and Sergey V. Lindeman
Formation of Bicyclic Pyrroles from the Catalytic Coupling Reaction of 2,5-disubstituted Pyrroles with Terminal Alkynes, Involving the Activation of Multiple C-H bonds, Chase S. Yi and Jie Zhang
Chiral Ionic Liquids: Synthesis, Properties, and Enantiomeric Recognition, Shaofang Yu, Sergey V. Lindeman, and Chieu D. Tran
Polymerically Modified Layered Silicates: An Effective Route to Nanocomposites, Jinguo Zhang, Evangelos Manias, and Charles A. Wilkie
Submissions from 2007
Chemistry and Biology of Streptogramin A Antibiotics, Fahim Ahmed and William A. Donaldson
Practical Synthesis of Unsymmetrical Tetraarylethylenes and Their Application for the Preparation of [Triphenylethylene−Spacer−Triphenylethylene] Triads, Moloy Banerjee, Susanna J. Emond, Sergey V. Lindeman, and Rajendra Rathore
Structural Characterization of Quaterphenyl Cation Radical: X-ray Crystallographic Evidence of Quinoidal Charge Delocalization in Poly-p-phenylene Cation Radicals, Moloy Banerjee, Sergey V. Lindeman, and Rajendra Rathore
The Crystal and Molecular Structure of a Trifluoroacetylacetonate Complex of Scandium, Sc(CH3COCHCOCF3)3, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and Sergey V. Lindeman
Generation of molecular complexity from cyclooctatetraene: synthesis of a protected 2-(3′-carboxy-2′-benzoylcyclopentyl)glycine, Subhabrata Chaudhury, Sergey V. Lindeman, and William A. Donaldson
Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations, Subhabrata Chaudhury, Shukun Li, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William A. Donaldson
Revealing Nano-confinement in Degradation and Relaxation Studies of Two Structurally Different Polystyrene-Clay Systems, Kai Chen, Charles A. Wilkie, and Sergey Vyazovkin
Enhanced Fire Retardancy of Vinyl Ester Resins by Combination of Additives, Grace Chigwada and Charles A. Wilkie
The Influence of Carbon Nanotubes, Organically Modified Montmorillonites and Layered Double Hydroxides on the Thermal Degradation and Fire Retardancy of Polyethylene, Ethylene-Vinyl Acetate Copolymer and Polystyrene, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Giovanni Camino, Alberto Frache, Gunter Beyer, Rakesh K. Gupta, and Charles A. Wilkie
Benzimidazolium Surfactants for Modification of Clays for Use with Styrenic Polymers, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Rakesh K. Gupta, and Charles A. Wilkie
Hexabenzo[4.4.4]propellane: A Helical Molecular Platform for the Construction of Electroactive Materials, Paromita Debroy, Sergey V. Lindeman, and Rajendra Rathore
Preparation of Chiral Cholestanofluorene and Its Electron-Rich Derivatives for Isolation of a Stable Cation−Radical Salt, Paromita Debroy, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore
The Voltammetric Study of the Reduction of Tetraalkylammonium Perchlorate by Fe(TPP)2-, Chathra Shirani De Silva and Michael D. Ryan
A ‘Metallic Tape’ Stabilized by an Unprecedented μ5-κ2,κ2,κ2,κ1,κ1-) Scorpionate Binding Mode, James R. Gardinier, Rosalice M. Silva, Chengeto Gwengo, and Sergey V. Lindeman
Reactivity of [Re2(CO)8(MeCN)2] with Thiazoles: Hydrido Bridged Dirhenium Compounds Bearing Thiazoles in Different Coordination Modes, Shariff E. Kabir, Faruque Ahmed, Anamika Das, Mohammad R. Hassan, Daniel T. Haworth, Sergey V. Lindeman, G. M. Golzar Hossain, Tasneem Siddiquee, and Dennis W. Bennett
P–C and C–H Bond Cleavages of dppm in the Thermal Reaction of [Ru3(CO)10(μ-dppm)] with Benzothiophene: X-ray structures of [Ru6(μ-CO)(CO)13{μ4-PhP(C6H4)PPh}(μ6-C)] and [Ru4(CO)9(μ3-η2-PhPCH2PPh2)(μ4-η6:η1:η1-C6H4)(μ-H)], Shariff E. Kabir, Mohammad R. Hassan, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, and Dennis W. Bennett
A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I), Brendan J. Liddle, Sergey V. Lindeman, Daniel L. Reger, and James R. Gardinier
BORAZANs: Tunable Fluorophores Based on 2-(Pyrazolyl)aniline Chelates of Diphenylboron, Brendan J. Liddle, Rosalice M. Silva, Tyler James Morin, Felipe P. Macedo, Ruchi Shukla, Sergey V. Lindeman, and James R. Gardinier
Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle, Piotr J. Mak, Ilia G. Denisov, Doreen Victoria, Thomas M. Makris, Tianjing Deng, Stephen G. Sligar, and James R. Kincaid
Ferrocene and Ferrocenium Modified Clays and Their Styrene and EVA Composites, Charles Manzi-Nshuti and Charles A. Wilkie
Characterization of the Catalytically Active Mn(II)-loaded argE-encoded N-acetyl-L-ornithine Deacetylase from Escherichia coli, Wade C. McGregor, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz
Unraveling the Catalytic Mechanism of Nitrile Hydratases, Sanghamitra Mitra and Richard C. Holz
Practical Issues and Future Trends in Polymer Nanocomposite Flammability Research, Alexander B. Morgan and Charles A. Wilkie
X-ray Crystallographic Characterization of the Co(II)-substituted Tris-bound Form of the Aminopeptidase from Aeromonas proteolytica, Petra Munih, Aaron Moulin, Carin Stamper, Brian Bennett, Dagmar Ringe, Gregory A. Petsko, and Richard C. Holz
13C NMR Analysis of Biologically Produced Pyrene Residues by Mycobacterium sp. KMS in the Presence of Humic Acid, J. Karl C. Nieman, Richard C. Holz, and Ronald C. Sims
Conserved Amino Acids in Each Subunit of the Heteroligomeric tRNA m1A58 Mtase from Saccharomyces cerevisiae Contribute to tRNA Binding, Sarah G. Ozanick, Janusz M. Bujnicki, Daniel S. Sem, and James T. Anderson
Synthesis of Cyclopropanes via Organoiron Methodology: Stereoselective Preparation of Bi(cyclopropyl)s, Rajesh K. Pandey, Sergey V. Lindeman, and William A. Donaldson
Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of trans-Pt(Pet3)2(SePh)2, Martin D. Rudd and Sergey V. Lindeman
Use of Factor Analysis in Multi‐Electron Spectroelectrochemistry, Michael D. Ryan and Robert L. Keesey
Binding of an Acetonitrile Molecule Inside the Ethereal Cavity of a Hexaarylbenzene-Based Receptor via a Synergy of C–H⋯O/C–H⋯π Interactions, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore
Electron Transfer Prompted Ejection of a Tightly Bound K+ from the Ethereal Cavity of a Hexaarylbenzene-Based Receptor, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore
Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine Cpa, Tasneem A. Siddiquee, Julie Lukesh, Sergey Sergey Lindeman, and William A. Donaldson
Cycloaddition Reactions of Phthalimide Substituted Cyclic Polyenes with Heteroatom Dienophiles, Stephen S. Templin, Nathaniel J. Wallock, Daniel T. Haworth, William A. Donaldson, Dennis W. Bennett, and Tasneem Siddiquee
Mechanism of Rate-Limiting Motions in Enzyme Function, Eric D. Watt, Hiroko Shimada, Evgenii L. Kovrigin, and J. Patrick Loria
Submissions from 2006
Synergistic Use of Compound Properties and Docking Scores in Neural Network Modeling of CYP2D6 Binding: Predicting Affinity and Conformational Sampling, Peter S. Bazeley, Sridevi Prithivi, Craig Struble, Richard J. Povinelli, and Daniel S. Sem
Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C42H54O5• CH3CN, Dennis W. Bennett, Tasneem A. Siddiquee, Daniel T. Haworth, Subhabrata Chaudhury, and William A. Donaldson
Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones, Subhabrata Chaudhury and William A. Donaldson
Synthetic Studies Directed Toward the Proposed Structure for Heteroscyphic Acid A, Subhabrata Chaudhury, Shukun Li, and William A. Donaldson
Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene, Vincent J. Chebny, Dwairath Dhar, Sergey V. Lindeman, and Rajendra Rathore
Styrenic Nanocomposites Prepared using a Novel Biphenyl-Containing Clay, Grace Chigwada, Dongyan Wang, David D. Jiang, and Charles A. Wilkie
Polystyrene Nanocomposites Based on Quinolinium and Pyridinium Surfactants, Grace Chigwada, Dongyan Wang, and Charles A. Wilkie
Preparation and Characterization of Poly(Ethylene Terephtalate)/Clay Nanocomposites by Melt Blending using Thermally Stable Surfactants, Marius Cristian Costache, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie
Fire Retardancy of Polyureas, Marius Cristian Costache, Eric M. Kanugh, Charles A. Wilkie, and Usman Sorathia
The Thermal Degradation of Poly(methyl methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Marius C. Costache, Dongyan Wang, Matthew Heidecker, Evangelos Manias, and Charles A. Wilkie
Kinetic and Spectroscopic Characterization of the E134A- and E134D-altered dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase from Haemophilus influenzae, Ryan S. Davis, David L. Bienvenue, Sabina I. Swierczek, Danuta M. Gilner, Lakshman Rajagopal, Brian Bennett, and Richard C. Holz
The High-Resolution Structures of the Neutral and the Low pH Crystals of Aminopeptidase from Aeromonas proteolytica, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Gregory A. Petsko, Dagmar Ringe, and Richard C. Holz
The Proteomics of N-terminal Methionine Cleavage, Frédéric Frottin, Aude Martinez, Philippe Peynot, Sanghamitra Mitra, Richard C. Holz, Carmela Giglione, and Thierry Meinnel
Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS), JIanwei Hao, Menachem Lewin, Charles A. Wilkie, and Jiangqi Wang
Applications of Acoustic Wave Devices for Sensing in Liquid Environments, Jeanne Hossenlopp
Nanostructured Layered Copper Hydroxy Dodecyl Sulfate: A Potential Fire Retardant for Poly(vinyl Ester) (PVE), Everson Kandare, Grace Chigwada, Dongyan Wang, Charles A. Wilkie, and Jeanne Hossenlopp
Probing Synergism, Antagonism, and Additive Effects in Poly(vinyl Ester) (PVE) Composites with Fire Retardants, Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp
Thermal Stability and Degradation Kinetics of Poly(methyl Methacrylate)/Layered Copper Hydroxy Methacrylate Composites, Everson Kandare, Hongmei Deng, Dongyan Wang, and Jeanne Hossenlopp
Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts, Everson Kandare and Jeanne Hossenlopp
NMR Studies of Escherichia Coli Acyl Carrier Protein: Dynamic and Structural Differences of the Apo- and Holo-forms, Yangmee Kim, Evgenii L. Kovrigin, and Ziad Eletr
Faithful Estimation of Dynamics Parameters from CPMG Relaxation Dispersion Measurements, Evgenii L. Kovrigin, James G. Kempf, Michael J. Grey, and J. Patrick Loria
Characterization of the Transition State of Functional Enzyme Dynamics, Evgenii L. Kovrigin and J. Patrick Loria
Enzyme Dynamics Along the Reaction Coordinate: Critical Role of a Conserved Residue, Evgenii L. Kovrigin and J. Patrick Loria
Nanocomposites at Elevated Temperatures: Migration and Structural Changes, Menachem Lewin, E. M. Pearce, Kelle Levon, Abraham Mey-Marom, Mauro Zammarano, Charles A. Wilkie, and Bok Nam Jang
A New Colorimetric Assay for Methionyl Aminopeptidases: Examination of the Binding of a New Class of Pseudopeptide Analog Inhibitors, Sanghamitra Mitra, Anna M. Dygas-Holz, Jiri Jiracek, Miroslava Zertova, Lenka Zakova, and Richard C. Holz
Attachment of Motile Bacterial Cells to Prealigned Holed Microarrays, Sergey Rozhok, Zhifang Fan, Dorjderem Nyamjav, Chang Liu, Chad A. Mirkin, and Richard C. Holz
The Redox Couple of the Cytochrome c Cyanide Complex: The Contribution of Heme Iron Ligation to the Structural Stability, Chemical Reactivity, and Physiological Behavior of Horse Cytochrome c, Abel Schejter, Michael D. Ryan, Erica R. Blizzard, Chongyao Zhang, Emanuel Margoliash, and Benjamin A. Feinberg
A Practical Synthesis of Bridged Diarylacetylenes, Ruchi Shukla, Daniel M. Brody, Sergey V. Lindeman, and Rajendra Rathore
A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction, Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore
Janus Scorpionates: Supramolecular Tectons for the Directed Assembly of Hard−Soft Alkali Metallopolymer Chains, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier
Ligand-Promoted Solvent-Dependent Ionization and Conformational Equilibria of Re(CO)3Br[CH2(S-tim)2] (tim = 1-methylthioimidazolyl). Crystal Structures of Re(CO)3Br[CH2(S-tim)2] and {Re(CO)3(CH3CN)[CH2(S-tim)2]}(PF6), Rosalice M. Silva, Brendan J. Liddle, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier
Novel Potentiometric and Optical Silver Ion-selective Sensors with Subnanomolar Detection Limits, Zsófia Szigeti, Adam Malon, Tamás Vigassy, Viktor Csokai, Alajos Grün, Katarzyna Wygladacz, Nan Ye, Chao Xu, Vincent J. Chebny, István Bitter, Rajendra Rathore, Eric Bakker, and Ernö Pretsch
TGA analysis of γ-Irradiated Linear Low Density Polyethylene, Adams Tidjani and Charles A. Wilkie
Synthesis of Cyclopropanes via Organoiron Methodology: Preparation and Rearrangement of Divinylcyclopropanes - Studies Directed toward the Synthesis of Hydroazulenes, Nathaniel J. Wallock, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William A. Donaldson
Fire Properties of Polymer Nanocomposites, Charles A. Wilkie
High-Throughput Techniques for the Evaluation of Fire Retardancy, Charles A. Wilkie, Grace Chigwada, Jeffery W. Gilman Sr., and Richard E. Lyon
A Review of Recent Work in the Fire Retardancy of Nanocomposites, Charles A. Wilkie, Xiaoxia Zheng, Grace Chigwada, Marius C. Costache, Bok Nam Jang, and Jinguo Zhang
Highly Cooperative Tetrametallic Ruthenium-μ-Oxo-μ-Hydroxo Catalyst for the Alcohol Oxidation Reaction, Chae S. Yi, Tonya N. Zeczycki, and Ilia A. Guzei
Controlled Silylation of Montmorillonite and its Polyethylene Nanocomposites, Jinguo Zhang, Rakesh K. Gupta, and Charles A. Wilkie
Styrenic Polymer Nanocomposites Based on an Oligomerically-Modified Clay with High Inorganic Content, Jinguo Zhang, David D. Jiang, Dongyan Wang, and Charles A. Wilkie
Fire properties of styrenic polymer–clay nanocomposites based on an oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie
Polyethylene and polypropylene nanocomposites based on a three component oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie
Thermal and Flame Properties of Polyethylene and Polypropylene Nanocomposites Based on an Oligomerically–Modified Clay, Jinguo Zhang, David D. Jiang, and Charles A. Wilkie
Fire Retardancy of Polypropylene-Metal Hydroxide Nanocomposites, Jinguo Zhang and Charles A. Wilkie