The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2001

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Photooxidation of Polymeric-inorganic nanocomposites: Chemical, Thermal Stability and Fire Retardancy Investigations, Adams Tidjani and Charles A. Wilkie

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The Thermal Stability Of Cross-Linked Polymers: Methyl Methacrylate With Divinylbenzene and Styrene With Dimethacrylates, Fawn Marie Uhl, Galina F. Levchik, Sergei V. Levchik, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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Noncovalent Binding of the Halogens to Aromatic Donors. Discrete Structures of Labile Br2 Complexes with Benzene and Toluene, Alexandr V. Vasilyev, Sergey V. Lindeman, and Jay K. Kochi

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PVC-Clay nanocomposites: Preparation, Thermal and Mechanical Properties, Dongyan Wang, Daniel Parlow, Qiang Yao, and Charles A. Wilkie

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XPS Characterization of Friedel-Crafts Cross-Linked Polystyrene, Jiangqi Wang, Jianxin Du, Hongyang Yao, and Charles A. Wilkie

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Electrochemistry and spectroelectrochemistry of iron porphyrins in the presence of nitrite, Zhongcheng Wei and Michael D. Ryan

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Graft Copolymerization as a Tool for Flame Retardancy, Charles A. Wilkie

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Fire Retardancy in 2001, Gordon L. Wilson and Charles A. Wilkie

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Cross-linking of Polystyrene by Friedel-Crafts Chemistry: Reaction of p-Hydroxymethylbenzyl Chloride with Polystyrene, Hongyang Yao, Michael A. McKinney, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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Cross-Linking of Polystyrene by Friedel-Crafts Chemistry: A Review, Hongyang Yao and Charles A. Wilkie

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Thermal Degradation Of PVC In The Presence Of Polystyrene, Qiang Yao and Charles A. Wilkie

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Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation, Young K. Yun, Heiko Bärmann, and William Donaldson

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Fire Properties of Polystyrene-Clay Nanocomposites, Jin Zhu, Alexander B. Morgan, Frank K. Lamelas, and Charles A. Wilkie

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Studies on the mechanism by which the formation of nanocomposites enhance thermal stability, Jin Zhu, Fawn Marie Uhl, Alexander B. Morgan, and Charles A. Wilkie

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Recent Studies on Thermal Stability and Flame Retardancy of Polystyrene-Nanocomposites, Jin Zhu, Fawn Marie Uhl, and Charles A. Wilkie

Submissions from 2000

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Development of Organoiron Methodology for Preparation of the Polyene Natural Product Macrolactin A, Heiko Bärmann, Vadapalli Prahlad, Chunlin Tao, Young K. Yun, Zhi Wang, and William Donaldson

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by l-leucinethiol: Kinetic and Spectroscopic Characterization of a Slow, Tight-binding Inhibitor–enzyme Complex, David L. Bienvenue, Brian Bennett, and Richard C. Holz

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Stoichiometric Applications of Acyclic p-Organoiron Complexes to Organic Synthesis, William Donaldson

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Reaction of Alkynes with Tetracarbonyl[Methoxy(2,4-Dimethoxyphenyl)Carbene]chromium: A Formal Synthesis of 7-Methoxyeleutherin, Karl Heinz Dötz, William Donaldson, and Werner Sturm

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Divalent Metal Binding Properties of the Methionyl Aminopeptidase from Escherichia coli, Ventris M. D'Souza, Brian Bennett, Alicja J. Copik, and Richard C. Holz

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Phorboxazole synthetic studies: the C3–C15 bis-oxane segment, Patrick Bernard Greer and William Donaldson

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Charge-Transfer Bonding in Metal–Arene Coordination, S. M. Hubig, Sergey V. Lindeman, and Jay K. Kochi

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Thermal degradation of Cross-Linked Polyisoprene and Polychloroprene, David D. Jiang, Galina F. Levchik, Sergei V. Levchik, Caroline Dick, John J. Liggat, C.E. Snape, and Charles A. Wilkie

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On the Stabilizing Action of Protein Denaturants: Acetonitrile Effect on Stability of Lysozyme in Aqueous Solutions, Evgueni Kovriguine and Sergey A. Potekhin

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Char Formation, Sergei V. Levchik and Charles A. Wilkie

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Electrophilic Aromatic Nitrosation. Isolation and X-ray Crystallography of the Metastable NO+ Complex With Nitrosoarene, Sergey V. Lindeman, E. Bosch, and Jay K. Kochi

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Silver(I) Complexation of (Poly)aromatic Ligands. Structural Criteria for Depth Penetration into cis-Stilbenoid Cavities, Sergey V. Lindeman, Rajendra Rathore, and Jay K. Kochi

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Novel Charge-Transfer Materials via Cocrystallization of Planar Aromatic Donors and Spherical Polyoxometalate Acceptors, P. Le Maguères, S. M. Hubig, Sergey V. Lindeman, P. Peya, and Jay K. Kochi

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Novel (Heteromolecular) π-Complexes of Aromatic Cation Radicals. Isolation and Structural Characterization, P. Le Maguères, Sergey V. Lindeman, and Jay K. Kochi

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Reaction of tricarbonyl(dienal)iron complexes with B-allyldiisopinocampheylborane, Vadapalli Prahlad, Abdel-Aziz S. El-Ahl, and William Donaldson

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Polybutadiene Cross-Linked With Various Diols – Effect On Thermal Stability, Fawn Marie Uhl, Michael A. McKinney, and Charles A. Wilkie

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Cross-linking of Polystyrene by Friedel-Crafts Chemistry: Multi-functional Additives, Hongyang Yao, Jin Zhu, Michael A. McKinney, and Charles A. Wilkie

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How does Cross-Linking Effect the Thermal Stability of Polyisoprene, Qiang Yao and Charles A. Wilkie

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Thermal and Fire Studies on Polystyrene-Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 1999

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Thermal Decomposition and Combustion of γ-irradiated Polyamide 6 Containing Phosphorus Oxynitride or Phospham, A. I. Balabanovich, Sergei V. Levchik, Galina F. Levchik, W. Schnabel, and Charles Wilkie

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1-Butaneboronic Acid Binding to Aeromonas proteolytica Aminopeptidase:  A Case of Arrested Development, Carin C. De Paola, Brian Bennett, Richard C. Holz, Dagmar Ringe, and Gregory A. Petsko

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The Methionyl Aminopeptidase from Escherichia coli Can Function as an Iron(II) Enzyme, Ventris M. D'Souza and Richard C. Holz

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Synthesis and Reactivity of Acyclic (pentadienyl)iron(1+) Cations: Model Studies for the Preparation of the 8E,10Z,16E,18E-Tetraene Segment of Macrolactin A, Abdel-Aziz S. El-Ahl, Young Yun, and William Donaldson

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An XPS Study of the Radiation-induced Effect on the Thermal Degradation and Charring of Butadiene and its Copolymers, JIanwei Hao, Shaoli Wu, Charles Wilkie, and Jianqi Wang

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1H NMR Studies on the CuA Center of Nitrous Oxide Reductase from Pseudomonas stutzeri, Richard C. Holz, Marcela L. Alvarez, Walter G. Zumft, and David M. Dooley

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Slow-Binding Inhibition of the Aminopeptidase from Aeromonas proteolytica by Peptide Thiols: Synthesis and Spectroscopic Characterization, Kristi M. Huntington, David L. Bienvenue, Yaoming Wei, Brian Bennett, Richard C. Holz, and Dehua Pei

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Thermal Decomposition of Cross-linked Polybutadiene and its Copolymers, David D. Jiang, Galina F. Levchik, Sergei V. Levchik, and Charles Wilkie

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TGA/FTIR Studies on the Thermal Degradation of some Polymeric Sulfonic and Phosphonic Acids and Their Sodium Salts, David D. Jiang, Qiang Yao, Michael A. McKinney, and Charles Wilkie

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Use of Evolutionary Factor Analysis in the Spectroelectrochemistry of Escherichia coli Sulfite Reductase Hemoprotein and a Mo/Fe/S Cluster, Robert L. Keesey and Michael D. Ryan

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Thermal Degradation of Polystyrene, Poly(1,4-butadiene) and Copolymers of Styrene and 1,4-butadiene Irradiated Under Air or Argon with 60Co-γ-rays, W. Schnabel, Galina F. Levchik, Charles Wilkie, David D. Jiang, and Sergei V. Levchik

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Visible and Resonance Raman Spectra of Low Valent Iron Porphyrins, Chathra De Silva, Kazimierz Czarnecki, and Michael D. Ryan

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by Aliphatic Alcohols. Characterization of the Hydrophobic Substrate Recognition Site, Leila Ustynyuk, Brian Bennett, Tanya Edwards, and Richard C. Holz

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Cross-linking of Polystyrene by Friedel–Crafts Chemistry to Improve Thermal Stability, Zhitao Wang, David D. Jiang, Michael A. McKinney, and Charles Wilkie

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Further Studies on Fire Retardant Polystyrene by Friedel–Crafts Chemistry, Zhitao Wang, David D. Jiang, Charles Wilkie, and Jeffery W. Gilman

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Adventures in Fire retardancy, Charles A. Wilkie

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TGA/FTIR: An Extremely Useful Technique for Studying Polymer Degradation, Charles A. Wilkie

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Thermal Degradation of Blends of Polystyrene and poly(sodium 4-styrenesulfonate) and the copolymer, poly(styrene-co-sodium 4-styrenesulfonate), Qiang Yao and Charles Wilkie

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X-ray Crystal Structures and the Facile Oxidative (Au−C) Cleavage of the Dimethylaurate(I) and Tetramethylaurate(III) Homologues, Dunming Zhu, Sergey V. Lindeman, and Jay K. Kochi

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Stabilization of Polystyrene by Friedel-Crafts Chemistry: Effect of Position of Alcohol and the Catalyst, Jin Zhu, Michael A. McKinney, and Charles Wilkie

Submissions from 1998

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Inhibition of the Aminopeptidase from Aeromonas proteolytica by l-Leucinephosphonic Acid, a Transition State Analogue of Peptide Hydrolysis, Brian Bennett and Richard C. Holz

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Photoinduced Coupling of Acetylenes and Quinone in the Solid State as Preorganized Donor−Acceptor Pairs, E. Bosch, S. M. Hubig, Sergey V. Lindeman, and Jay K. Kochi

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Chemoselective, Metal-Mediated Oxidation of (dienol)iron Complexes with N-methylmorpholine N-oxide, Bireshwar Dasgupta and William Donaldson

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Synthetic Studies Directed Toward Streptenol D: Enantioselective Preparation of the 3,5-diacetoxy-6E,8E-decadiene Segment, Bireshwar Dasgupta and William Donaldson

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TGA–FTi.r. investigation of the thermal degradation of Nafion® and Nafion®/[silicon oxide]-based nanocomposites, Q. Deng, Charles Wilkie, R. B. Moore, and Kenneth A. Mauritz

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Direct Voltammetric Observation of Redox Driven Changes in Axial Coordination and Intramolecular Rearrangement of the Phenylalanine-82-Histidine Variant of Yeast Iso-1-cytochrome c, Benjamin A. Feinberg, Xiangjun Liu, Michael D. Ryan, Abel Schejter, Chongyao Zhang, and Emanuel Margoliash

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Direct Voltammetric Observation of Redox Driven Changes in Axial Coordination and Intramolecular Rearrangement of the Phenylalanine-82-Histidine Variant of Yeast Iso-1-cytochrome c, Benjamin A. Feinberg, Xiangjun Liu, Michael D. Ryan, Abel Schejter, Chongyao Zhang, and Emanuel Margoliash

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The CuA Center of a Soluble Domain from Thermus cytochrome ba3. An NMR Investigation of the Paramagnetic Protein. A Proton NMR Study of the Paramagnetic Active Site of the CuA Variant of Amicyanin, Richard C. Holz

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Proton NMR Spectroscopy as a Probe of Dinuclear Copper(II) Active Sites in Metalloproteins. Characterization of the Hyperactive Copper(II)-Substituted Aminopeptidase from Aeromonas proteolytica, Richard C. Holz, Brian Bennett, Guanjing Chen, and Li-June Ming

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Synthesis, Molecular Structure, and Reactivity of Dinuclear Copper(II) Complexes with Carboxylate-Rich Coordination Environments, Richard C. Holz, John M. Bradshaw, and Brian Bennett

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Graft Copolymerization of Methacrylic Acid, Acrylic Acid and Methyl Acrylate onto Styrene–Butadiene Block Copolymer, David D. Jiang and Charles Wilkie

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Structure of 5-nitro-2-tosylaminobenzaldehyde di(morpholin-4-yl)aminal Complex with Carbon Tetrachloride, V. N. Khrustalev, Sergey V. Lindeman, L. Yu Ukhin, G. I. Orlova, T. N. Gribanova, and O. V. Shishkin

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Surface Modification of Polyamide-6: Graft Copolymerization of Vinyl Monomers onto Polyamide-6 and Thermal Analysis of the Graft Copolymers, Nicole M. Langer and Charles A. Wilkie

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Unusually Short (C−H···π) Hydrogen Bonds for Effective Supramolecular (Aromatic/Aromatic) Organization in Edge-to-Face Motifs, Sergey V. Lindeman, D. Kosynkin, and Jay K. Kochi

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Chemical and Electrochemical Studies of Cl2FeS2MS2FeCl2n- Clusters [M = Mo (n = 2), W (n = 2), V (n = 3)], Yanming Liu, Jinhai Chen, and Michael D. Ryan

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Chemical and Electrochemical Studies of Cl2FeS2MS2FeCl2n- Clusters [M = Mo (n = 2), W (n = 2), V (n = 3)], Yanming Liu, Jinhai Chen, and Michael D. Ryan

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X-Ray Structure of Bridged 2,2′-Bi(Adamant-2-ylidene) Chloronium Cation and Comparison of its Reactivity with a Singly-Bonded Chloroarenium Cation, T. Mori and Rajendra Rathore

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Effect of Kinetic Factors on Heat Denaturation and Renaturation of Biopolymers, Sergey A. Potekhin and Evgueni Kovriguine

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Folding Under Inequilibrium Conditions as a Possible Reason for Partial Irreversibility of Heat-Denatured Proteins: Computer Simulation Study, Sergey A. Potekhin and Evgueni Kovriguine

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Preparation and Structures of Crystalline Aromatic Cation-Radical Salts. Triethyloxonium Hexachloroantimonate as a Novel (One-Electron) Oxidant, Rajendra Rathore, A. S. Kumar, Sergey V. Lindeman, and Jay K. Kochi

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Disproportionation and Structural Changes of Tetraarylethylene Donors upon Successive Oxidation to Cation Radicals and to Dications, Rajendra Rathore, Sergey V. Lindeman, A. S. Kumar, and Jay K. Kochi

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Novel Synthesis and Structures of Tris-Annelated Benzene Donors for the Electron-Density Elucidation of the Classical Mills−Nixon Effect, Rajendra Rathore, Sergey V. Lindeman, A. S. Kumar, and Jay K. Kochi

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Synthesis and Characterization of Large Stereoregular Organosiloxane Cycles, O. I. Schchegolikhina, V. A. Igonin, Yulia A. Molodtsova, Yu. A. Pozdniakova, Alexandr A. Zhdanov, T. V. Strelkova, and Sergey V. Lindeman

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Studies on the Preparation of Protomycinolide IV: Enantioselective Synthesis of the C3–C9 Segment, James Thomas Wasicak and William Donaldson

Submissions from 1997

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Remote Diastereoselective Control via Organoiron Methodology: Stereoselective Preparation of 4,6-, 5,7- and 6,8-dien-2-ol (tricarbonyl) Iron Complexes, Peter Thomas Bell, Bireshwar Dasgupta, and William Donaldson

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EPR Studies on the Mono- and Dicobalt(II)-Substituted Forms of the Aminopeptidase from Aeromonas proteolytica. Insight into the Catalytic Mechanism of Dinuclear Hydrolases, Brian Bennett and Richard C. Holz

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Spectroscopically Distinct Cobalt(II) Sites in Heterodimetallic Forms of the Aminopeptidase from Aeromonas proteolytica:  Characterization of Substrate Binding, Brian Bennett and Richard C. Holz

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Mechanistic Studies on the Aminopeptidase from Aeromonas proteolytica:  A Two-Metal Ion Mechanism for Peptide Hydrolysis, Guanjing Chen, Tanya Edwards, Ventris M. D'Souza, and Richard C. Holz

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Reactions of Hydroxylamine with Metal Porphyrins, In Kyu Choi, Yanming Liu, Zhongcheng Wei, and Michael D. Ryan

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Preparation and Reactivity of Acyclic (Pentadienyl)iron(1+) Cations: Applications to Organic Synthesis, William A. Donaldson

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Synthesis and Characterization of tricarbonyl(trimethylenemethane)iron complexes: crystal structure of (2-methylene-6-p-nitrobenzoyloxy-heptan-1,3-diyl)Fe(CO)3, William A. Donaldson, Charles D. Cushnie, Shu Guo, Mark J. Kramer, and Dennis W. Bennett

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Reactivity of 1-Substituted (pentadienyl)iron(1+) Cations: Regioselectivity for Addition of Malonate Nucleophiles; Formation of (pentenediyl)- and (diene) Iron Complexes, William Donaldson, Lewei Shang, Chunlin Tao, Young K. Yun, Muthukumar Ramaswamy, and Victor G. Young Jr.

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Proton Nuclear Magnetic Resonance Investigation of the [2Fe-2S]1--Containing “Rieske-Type” Protein from Xanthobacter Strain Py2, Richard C. Holz, Frederick J. Small, and Scott A. Ensign

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N-Methylbenzothiazole-2(3H)-selone, C8H7NSSe, Steinar Husebye, Sergey V. Lindeman, and Martin D. Rudd

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Chemical Initiation of Graft Copolymerization of Methyl Methacrylate onto Styrene–butadiene Block Copolymer, David D. Jiang and Charles Wilkie

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Preparation of Organometallic Complexed Sugars:  Hetero Diels−Alder Reactivity of Tricarbonyl(formyltrimethylenemethane)- iron, Paul J. Kleindl and William Donaldson

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Synthesis, Structures, and Properties of Spiro[6-Azaperimidine-2,4′-Cyclohexa-2′,5′-Dien]-1′-One Derivatives, V. N. Komissarov, E. N. Gruzdeva, L. P. Olekhnovich, G. S. Borodkin, V. N. Khrustalev, Sergey V. Lindeman, Yu T. Struchkov, V. A. Kogan, and V. I. Minkin

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Molecular Structure and Conformational Dynamics of 3,12-dichloro-5,14-diphenyl-7,9a,16,18a-tetrazadibenzo[a,l]pentacene-9, 18-dione, A. Yu. Kovalevsky, O. V. Shishkin, I. A. Ronova, Igor I. Ponomarev, Sergey V. Lindeman, and Yu. A. Volkova

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Preferential Solvation Changes upon Lysozyme Heat Denaturation in Mixed Solvents, Evgueni Kovriguine and Sergey A. Potekhin

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Improving the Thermal Stability of Polystyrene by Friedel-Crafts Chemistry, Jinming Li and Charles Wilkie

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Hexakis(dimethylformamide)bis(hexaphenylcyclohexasiloxanehexaolato)hexacopper(II) Dimethylformamide Solvate, Sergey V. Lindeman, Olga I. Shchegolikhina, Yulia A. Molodtsova, and Alexandr A. Zhdanov

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Electrochemistry of Nitrite Reductase Model Compounds 6. Voltammetric and Spectroelectrochemical Studies of Iron(II) Nitrosyl Complexes with Porphyrins, Hydroprophyrins and Porphinones, Yanming Liu, Chathra DeSilva, and Michael D. Ryan

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Charge-Transfer Probes for Molecular Recognition via Steric Hindrance in Donor-Acceptor Pairs, Rajendra Rathore, Sergey V. Lindeman, and Jay K. Kochi

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Tautomeric Conversion of a Thiourea Ligand upon Formation of a Hypervalent Tellurium (II) Complex. Synthesis, and X-ray Structural Studies of N-Phenyl-N’-(1,3-Thiazol-2-YL)-Thiourea and Bromophenyl [1-Phenyl-3-(1’,3’-Thiazol-3’-ium-2’-YL)-isothioureidato]tellurium, Martin D. Rudd, Sergey V. Lindeman, and Steinar Husebye

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The Electrochemical Oxidation of Organic Selenides and Selenoxides, Michael D. Ryan, Jiyi Yau, and Michael Hack

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Alkylation of Tricarbonyl(diene)iron Complexes: Model Studies for the Preparation of Protomycinolide IV, James Thomas Wasicak, Richard A. Craig, Rodger Henry, Bireshwar Dasgupta, Huameng Li, and William Donaldson