The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 1998

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Novel Synthesis and Structures of Tris-Annelated Benzene Donors for the Electron-Density Elucidation of the Classical Mills−Nixon Effect, Rajendra Rathore, Sergey V. Lindeman, A. S. Kumar, and Jay K. Kochi

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Synthesis and Characterization of Large Stereoregular Organosiloxane Cycles, O. I. Schchegolikhina, V. A. Igonin, Yulia A. Molodtsova, Yu. A. Pozdniakova, Alexandr A. Zhdanov, T. V. Strelkova, and Sergey V. Lindeman

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Studies on the Preparation of Protomycinolide IV: Enantioselective Synthesis of the C3–C9 Segment, James Thomas Wasicak and William Donaldson

Submissions from 1997

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Remote Diastereoselective Control via Organoiron Methodology: Stereoselective Preparation of 4,6-, 5,7- and 6,8-dien-2-ol (tricarbonyl) Iron Complexes, Peter Thomas Bell, Bireshwar Dasgupta, and William Donaldson

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EPR Studies on the Mono- and Dicobalt(II)-Substituted Forms of the Aminopeptidase from Aeromonas proteolytica. Insight into the Catalytic Mechanism of Dinuclear Hydrolases, Brian Bennett and Richard C. Holz

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Spectroscopically Distinct Cobalt(II) Sites in Heterodimetallic Forms of the Aminopeptidase from Aeromonas proteolytica:  Characterization of Substrate Binding, Brian Bennett and Richard C. Holz

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Mechanistic Studies on the Aminopeptidase from Aeromonas proteolytica:  A Two-Metal Ion Mechanism for Peptide Hydrolysis, Guanjing Chen, Tanya Edwards, Ventris M. D'Souza, and Richard C. Holz

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Reactions of Hydroxylamine with Metal Porphyrins, In Kyu Choi, Yanming Liu, Zhongcheng Wei, and Michael D. Ryan

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Preparation and Reactivity of Acyclic (Pentadienyl)iron(1+) Cations: Applications to Organic Synthesis, William A. Donaldson

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Synthesis and Characterization of tricarbonyl(trimethylenemethane)iron complexes: crystal structure of (2-methylene-6-p-nitrobenzoyloxy-heptan-1,3-diyl)Fe(CO)3, William A. Donaldson, Charles D. Cushnie, Shu Guo, Mark J. Kramer, and Dennis W. Bennett

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Reactivity of 1-Substituted (pentadienyl)iron(1+) Cations: Regioselectivity for Addition of Malonate Nucleophiles; Formation of (pentenediyl)- and (diene) Iron Complexes, William Donaldson, Lewei Shang, Chunlin Tao, Young K. Yun, Muthukumar Ramaswamy, and Victor G. Young Jr.

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Proton Nuclear Magnetic Resonance Investigation of the [2Fe-2S]1--Containing “Rieske-Type” Protein from Xanthobacter Strain Py2, Richard C. Holz, Frederick J. Small, and Scott A. Ensign

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N-Methylbenzothiazole-2(3H)-selone, C8H7NSSe, Steinar Husebye, Sergey V. Lindeman, and Martin D. Rudd

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Chemical Initiation of Graft Copolymerization of Methyl Methacrylate onto Styrene–butadiene Block Copolymer, David D. Jiang and Charles Wilkie

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Preparation of Organometallic Complexed Sugars:  Hetero Diels−Alder Reactivity of Tricarbonyl(formyltrimethylenemethane)- iron, Paul J. Kleindl and William Donaldson

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Synthesis, Structures, and Properties of Spiro[6-Azaperimidine-2,4′-Cyclohexa-2′,5′-Dien]-1′-One Derivatives, V. N. Komissarov, E. N. Gruzdeva, L. P. Olekhnovich, G. S. Borodkin, V. N. Khrustalev, Sergey V. Lindeman, Yu T. Struchkov, V. A. Kogan, and V. I. Minkin

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Molecular Structure and Conformational Dynamics of 3,12-dichloro-5,14-diphenyl-7,9a,16,18a-tetrazadibenzo[a,l]pentacene-9, 18-dione, A. Yu. Kovalevsky, O. V. Shishkin, I. A. Ronova, Igor I. Ponomarev, Sergey V. Lindeman, and Yu. A. Volkova

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Preferential Solvation Changes upon Lysozyme Heat Denaturation in Mixed Solvents, Evgueni Kovriguine and Sergey A. Potekhin

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Improving the Thermal Stability of Polystyrene by Friedel-Crafts Chemistry, Jinming Li and Charles Wilkie

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Hexakis(dimethylformamide)bis(hexaphenylcyclohexasiloxanehexaolato)hexacopper(II) Dimethylformamide Solvate, Sergey V. Lindeman, Olga I. Shchegolikhina, Yulia A. Molodtsova, and Alexandr A. Zhdanov

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Electrochemistry of Nitrite Reductase Model Compounds 6. Voltammetric and Spectroelectrochemical Studies of Iron(II) Nitrosyl Complexes with Porphyrins, Hydroprophyrins and Porphinones, Yanming Liu, Chathra DeSilva, and Michael D. Ryan

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Charge-Transfer Probes for Molecular Recognition via Steric Hindrance in Donor-Acceptor Pairs, Rajendra Rathore, Sergey V. Lindeman, and Jay K. Kochi

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Tautomeric Conversion of a Thiourea Ligand upon Formation of a Hypervalent Tellurium (II) Complex. Synthesis, and X-ray Structural Studies of N-Phenyl-N’-(1,3-Thiazol-2-YL)-Thiourea and Bromophenyl [1-Phenyl-3-(1’,3’-Thiazol-3’-ium-2’-YL)-isothioureidato]tellurium, Martin D. Rudd, Sergey V. Lindeman, and Steinar Husebye

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The Electrochemical Oxidation of Organic Selenides and Selenoxides, Michael D. Ryan, Jiyi Yau, and Michael Hack

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Alkylation of Tricarbonyl(diene)iron Complexes: Model Studies for the Preparation of Protomycinolide IV, James Thomas Wasicak, Richard A. Craig, Rodger Henry, Bireshwar Dasgupta, Huameng Li, and William Donaldson

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Lithiation–alkylation of Polystyrene Occurs Only on the Ring, Thomas J. Xue, Mark S. Jones, John R. Ebdon, and Charles Wilkie

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The Thermal Degradation of Polyacrylonitrile, Thomas J. Xue, Michael A. McKinney, and Charles Wilkie

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Graft Copolymerization of Acrylonitrile onto Polystyrene, Thomas J. Xue and Charles Wilkie

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Thermal Degradation of Poly(styrene-g-acrylonitrile), Thomas J. Xue and Charles Wilkie

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Crystal and Molecular Structure of a Trisubstituted Cyclopropane: Dimethyl 2-methyl-2-[-2′-trans-methoxycarbonyl-3′-trans-(2″-p-nitrobenzoyloxyethyl)]-cyclopropylpropanedioate, C20H23NO10, Victor G. Young Jr., Young K. Yun, and William Donaldson

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An Unusual Stereochemical Outcome in the Oxidatively Induced Reductive Elimination of (Pentenediyl)iron Complexes, Young K. Yun and William Donaldson

Submissions from 1996

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Characterization of the Structural and Electronic Properties of Spin-Coupled Dinuclear Copper(II) Centers by Proton NMR Spectroscopy, Julie M. Brink, Rachel A. Rose, and Richard C. Holz

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Chemically Initiated Graft Copolymerization of Acrylic Acid onto Acrylonitrile-butadiene-styrene (ABS) Terpolymer and its Constituent Polymers, Jayakody A Chandrasiri and Charles Wilkie

Graft Copolymerization of Acrylic Acid on to Acrylonitrile-butadiene-styrene Terpolymer and Thermal Analysis of the Copolymers, Cyarthur Deacon and Charles Wilkie

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Dihydroxylation/glycol Cleavage of Tricarbonyl(triene)iron Complexes, William Donaldson and Lewei Shang

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μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P[sbnd]O[sbnd]P SEQUENCE, Thor Gramstad, Steinar Husebye, and Sergey Lindeman

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J-Dependent Curie or Anti-Curie Behavior of Proton NMR Resonances for Antiferromagnetically Coupled Dinuclear Copper(II) Complexes, Richard C. Holz, Julie M. Brink, and Rachel A. Rose

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Two-Dimensional 1H NMR Studies on Octahedral Nickel(II) Complexes, Richard C. Holz, Evgenij A. Evdokimov, and Feben T. Gobena

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Synthesis, Molecular Structure and Reactivity of a New Dicopper(II) Benzimidazole Complex with Non-Identical Copper(II) Sites, Richard C. Holz and Feben T. Gobena

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Bromobis(Diethyldithiocarbamato)(4-Methoxyphenyl)Tellurium(IV), Steinar Husebye, Thoralf Engebretsen, Martin D. Rudd, and Sergey V. Lindeman

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Bis(diethyldithiocarbamato)(iodo)(4-methoxyphenyl)tellurium(IV), p-MeOC6H4Te(Et2NCS2)2I, and its Isomorphous Partially Bromine-Replaced Analogue, p-MeOC6H4Te(Et2NCS2)2Br0.41I0.59, Steinar Husebye, Steffen Kudis, and Sergey V. Lindeman

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Bromobis(dimethyldithiocarbamato)(4-methoxyphenyl)tellurium(IV) Dichloromethane Hemisolvate, p-MeOC6H4Te(Me2NCS2)2Br.0.5CH2Cl2, Steinar Husebye, Steffen Kudis, and Sergey V. Lindeman

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Synthesis and X-ray Structural Study of 1-adamantylmethyl 2-cyanoacrylate and 1,10-decanediol bis-2-cyanoacrylate, V. N. Khrustalev, O. V. Shishkin, Sergey V. Lindeman, Yu T. Struchkov, M. A. Galkina, and Yu. G. Gololobov

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Synthesis and X-ray Structural Study of 1-adamantylmethyl 2-cyanoacrylate and 1,10-decanediol bis-2-cyanoacrylate, V. N. Khrustalev, O. V. Shishkin, Sergey V. Lindeman, Yu T. Struchkov, M. A. Galkina, and Yu. G. Gololobov

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Enthalpy of Stabilization of the Structure Hen's Egg Lysozyme in Aqueous Solutions of Dimethyl Sulphoxide, Evgueni Kovriguine, M. D. Kirkitadze, and Sergey A. Potekhin

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Microcalorimetric Study of the Effect of Dimethylsulphoxide on the Heat Denaturing of Lysozyme, Evgueni Kovriguine and Sergey A. Potekhin

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Synthesis of the C1-C8 Tetrahydropyranyl Segment of the Antifungal Agent Ambruticin and its C3 Epimer, Luping Liu and William Donaldson

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Molecular and Crystal Structure of 4,5,4′,5′-tetrahydro-2,2′-(1,4-phenylene) bisoxazoline, V. A. Pankratov, L. M. Mitina, Yu. E. Doroshenko, V. V. Yas'kevich, V. N. Khrustalev, and Sergey V. Lindeman

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Molecular and Crystal Structure of 4,5,4′,5′-tetrahydro-2,2′-(1,4-phenylene)bisoxazoline, V. A. Pankratov, L. M. Mitina, Yu. E. Doroshenko, V. V. Yas'kevich, V. N. Khrustalev, Sergey V. Lindeman, and Yu T. Struchkov

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Synthesis and Structure of 6-chloro-2,3-trimethylene-4-phenylquinoline, Igor I. Ponomarev, O. V. Shishkin, Sergey V. Lindeman, and Yu. V. Volkova

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Enantioselective Synthesis of the C11-C24 Segment of Macrolactin a via Organoiron Methodology, Vadapalli Prahlad and William Donaldson

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Synthesis and Crystal Structure of Dinitroxyl Crown Ether Biradical with Indole Groups in the Side Chains, A. B. Shapiro, V. I. Suskina, V. N. Khrustalev, Sergey V. Lindeman, and Yu T. Struchkov

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Cyclosiloxane Sandwich Complexes of a Lanthanide Metal: Na6{[(C6H5SiO2)8]2Nd4(μ4-O)}, Olga I. Shchegolikhina, Yu. A. Pozdniakova, Sergey V. Lindeman, Alexandr A. Zhdanov, R. Psaro, R. Ugo, G. Gavioli, R. Battistuzzi, M. Borsari, T. Rüffer, C. Zucchi, and G. Pályi

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Grafting to Achieve Flame Retardancy, Charles Wilkie, Masanori Suzuki, Xiaoxing Dong, Cyarthur Deacon, Jayakody A Chandrasiri, and Thomas J. Xue

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Crystal and Molecular Structure of 569-1569-1569-1, C12H16O5Fe, Victor G. Young Jr., Bireshwar Dasgupta, and William Donaldson

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Cyclooligosiloxanolate Cluster Complexes of Transition Metals and Lanthanides, C. Zucchi, Olga I. Shchegolikhina, M. Borsari, A. Cornia, G. Gavioli, A. C. Fabretti, E. Rentschler, D. Gatteschi, R. Ugo, R. Psaro, Yu. A. Pozdniakova, Sergey V. Lindeman, Alexandr A. Zhdanov, and G. Pályi

Submissions from 1995

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Structure and Conformational Flexibility of Hexamethyldiperoxacyclononane, V. L. Antonovsky, A. Yu. Kosnikov, I. L. Shamovskii, V. N. Khrustalev, Sergey Lindeman, and Yu T. Struchkov

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Synthesis of 12- and 13-Membered Sulfur-Containing Lactones by Homolytic Macrocyclization of Mercaptoacetic Esters with Alkynes, Dmitry V. Demchuk, Margarita I. Lazareva, Sergey Lindeman, Viktor N. Khrustalyov, Yurii T. Struchkov, Rustem F. Ismagilov, Emmanuil I. Troyansky, and Gennady I. Nikishin

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Iron-Mediated C-C Bond Formation. Preparation of (Trimethylenemethane)iron Complexes via Reaction of Weak Carbon Nucleophiles with in Situ Generated Cross-Conjugated Pentadienyl Cations. Nucleophilic Attack on (Trimethylenemethane)iron Complexes with Carbanions, William Donaldson, M. Azad Hossain, and Charles D. Cushnie

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Reactivity of (Pentadienyl)iron(1+) Cations: Nucleophilic Addition by Phosphines Is Reversible in Certain Cases, William Donaldson, Leiwei Shang, Muthukumar Ramaswamy, Christine A. Droste, Chunlin Tao, and Dennis W. Bennett

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Reactivity of (pentadienyl)iron(1+) Cations: Effect of Peripheral Ligands on the Regioselectivity of Nucleophilic Addition, William Donaldson and Lewei Shang

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Graft Copolymers of Methacrylic Acid and SBS and K-resin by the Anthracene Photosensitized Formation of Hydroperoxides, Xiaoxing Dong, Georges Geuskens, and Charles Wilkie

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Electrochemical cyclodimerization of alkylidenemalonates, Michail N. Elinson, Sergey K. Feducovich, Alexandre A. Zakharenkov, Bogdan I. Ugrak, Gennady I. Nikishin, Sergey Lindeman, and Jurii T. Struchkov

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Bimetallic siloxane cluster of higher valent transition metals: Na{[η6-cyclo-(PhSiO2)6]2Co2Ni46-Cl)}, G. Gavioli, R. Battistuzzi, P. Santi, C. Zucchi, G. Pályi, R. Ugo, A. Vizi-Orosz, O. I. Schchegolikhina, Yu. A. Pozdniakova, Sergey V. Lindeman, and Alexandr A. Zhdanov

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cis-(Diethyldithiocarbamato)diiodo(phenyl)tellurium(IV), PhTe(S2CNEt2)I2, and its Methoxy-Substituted Mixed Br/1 Analogue cis-Bis(0.4-bromo/0.6-iodo)-(diethyldithiocarbamato)(4-methoxyphenyl) tellurium(IV), p-MeOC6H4Te(S2 CNEt2)(Br0.4I0.6)2, Steinar Husebye, Steffen Kudis, Sergey V. Lindeman, and Peter Strauch

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Tris(diethyldithiocarbamato)(4-methoxyphenyl)tellurium(IV), p-MeOC6H4Te(S2CNEt2)3, and the Triclinic Modification of Tris(diethyldithiocarbamato)phenyltellurium(IV), PhTe(S2CNEt2)3, Steinar Husebye and Sergey V. Lindeman

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Reaction of stereoisomeric bis(cyclohexyl)-2,2′-diones with hydrogen peroxide: structure of the formed adducts, V. N. Khrustalev, Sergey V. Lindeman, Yu T. Struchkov, E. K. Starostin, A. V. Ignatenko, and Gennady I. Nikishin

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cis-6-Methoxycarbonyl-2,10-dioxa-1-phosphabicyclo[4.4.0]decane 1-Oxide, Thomas M. Lane, Oscar P Rodriguez, Anthony Gerard Sommese, Sheldon E. Cremer, and Dennis W. Bennett

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Proton NMR Investigation of the [4Fe-4S]1+ Cluster Environment of Nitrogenase Iron Protein from Azotobacter vinelandii: Defining Nucleotide-induced Conformational Changes, William N. Lanzilotta, Richard C. Holz, and Lance C. Seefeldt

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Macrobicyclic d-Metal Tris-Dioximates Obtained by Cross-linking with p-Block Elements. XV. Crystal and Molecular Structures of Two Macrobiocyclic Tin-containing Cobalt(III) Tris-Dioximates, Sergey Lindeman, Yuri T. Struchkov, and Yan Z. Voloshin

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Benz[4,5]Isoquino[1,2-b]Quinazoline-7,9-Dione and a Rearrangement Product of its Hydrolysis, 2-(1,8-Naphthalenedicarboximido)benzamide, Sergey V. Lindeman, Igor I. Ponomarev, and Alexandr L. Rusanov

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Carbocyclic and nitrogen-containing fused CH-acids with an annelated indenyl fragment. Thermogravimetric and X-ray structural analysis of 6H-indeno[1,2-b]quinoline, V. G. Pleshakov; V. M. Akimov; E. Huipe Nava; Sergey Lindeman; Yu T. Struchkov; K. D. Ambacheu; A. G. Dudareva; M. A. Ryashentseva; V. P. Zvolinsky; and N, S. Prostakov

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Conformational Analysis of 5,6-dihydropyrimidine and Its Derivatives, O. V. Shishkin, A. S. Polyakova, S. M. Desenko, D. V. Orlov, Sergey V. Lindeman, and Yu T. Struchkov

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Structures of Polymetallaorganosiloxanolates—a Novel Class of Organosilicon Metal Complexes, Yu T. Struchkov and Sergey V. Lindeman

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Graft Copolymerization of Methacrylic Acid and Acrylamide onto Acrylonitrile-butadiene-styrene Terpolymer by Photoinduced Hydroperoxide, Masanori Suzuki and Charles Wilkie

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The Thermal Degradation of Acrylonitrile-butadiene-styrene terpolymei as Studied by TGA/FTIR, Masanori Suzuki and Charles Wilkie

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The Thermal Degradation of Acrylonitri-lebutadiene-styrene terpolymer Grafted with Methacrylic Acid, Masanori Suzuki and Charles Wilkie

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Stereoselective Free Radical Cycloaddition-macrocyclization in Facile Synthesis of trans-cyclohexano-fused 12-membered Crown Thioethers, Emmanuil I. Troyansky, Rustem F. Ismagilov, Vyacheslav V. Samoshin, Yury A. Strelenko, Dmitry V. Demchuk, Gennady I. Nikishin, Sergey V. Lindeman, Viktor N. Khrustalyov, and Yury T. Struchkov

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Remote Asymmetric Induction in Free Radical Cycloaddition Leading to Trans-cyclohexano-fused 12-membered Crown Thioethers, Emmanuil I. Troyansky, Rustem F. Ismagilov, Yury A. Strelenko, Vyacheslav V. Samoshin, Dmitry V. Demchuk, Gennady I. Nikishin, Sergey V. Lindeman, Viktor N. Khrustalyov, and Yury T. Struchkov

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O-Tosylaminobenzaldehyde aminals in the synthesis of 1,3-disubstituted propargylamines, derivatives of 3H-2-vinylidene-3-aminoindoline and quinoline, L. Yu Ukhin, V. N. Komissarov, G. I. Orlova, G. S. Borodkin, Sergey Lindeman, V. N. Khrustalev, and Yu T. Struchkov

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Formation of H-bonded ionic associates in reactions of 5-nitrosalicylaldehyde with secondary amines, L. Yu Ukhin, G. I. Orlova, Sergey Lindeman, V. N. Khrustalev, and Yu T. Struchkov

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Swelling-assisted Modification of Poly(ethylene terephthalate) by Methacrylic Acid, Thomas J. Xue and Charles Wilkie

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The Interaction of Vinyl Monomers and Poly(ethylene terephthalate) in the Presence of Various Initiators Produces a Physical Mixture, not a Graft Copolymer, Thomas J. Xue and Charles Wilkie

Submissions from 1994

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Novel Organosilicon Betaines, I. V. Borisova; N. N. Zemlyanskii; Yu. A. Ustynyuk; V, N, Khrustalev; Sergey Lindeman; and Yu T. Struchkov

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The Effect of Some Transition Metal Chlorides on the Thermal Degradation of Poly(methyl methacrylate): A Study using TGA-FTIR Spectrometry, Jayakody A Chandrasiri, Dean E. Roberts, and Charles Wilkie

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Thermal Degradation of Diphenyl Disulfide and a Blend of Diphenyl Disulfide with Poly(methyl Methacrylate), Jayakody A Chandrasiri and Charles Wilkie

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Thermal Degradation of Poly(methyl methacrylate) in the Presence of Tin (IV) Chloride and Tetraphenyltin, Jayakody A Chandrasiri and Charles Wilkie

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The thermolysis of poly(methyl methacrylate) in the presence of phenyltin chlorides PhxSnCl4−x (x = 1–3), Jayakody A Chandrasiri and Charles Wilkie

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Reaction of Low-Valent Iron Porphyrins with Alkyl Containing Supporting Electrolytes, Chathra DeSilva, Kazimierz Czarnecki, and Michael D. Ryan

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Model Studies Toward the Synthesis of Macrolactin A: Organoiron Methodology for Introduction of the C1–C11 and C16–C24 Segments, William Donaldson, Peter Thomas Bell, Zhi Wang, and Dennis W. Bennett

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Reactivity of Tricarbonyl(pentadienyl)iron(1+) Cations: Preparation of an Optically Pure Tricarbonyl(diene)iron Complex via Second-Order Asymmetric Transformation, William Donaldson, Leiwei Shang, and Robin D. Rogers

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Proton NMR Spectroscopy as a Probe of Dinuclear Copper(II) Centers, Richard C. Holz and Julie M. Brink

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Dinuclear Copper(II) Complexes with Carboxylate-Rich Coordination Environments. Models for Substituted Copper(II) Aminopeptidases, Richard C. Holz, Julie M. Brink, Feben T. Gobena, and Charles J. O'Connor

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Study of Structural Aspects of Thermochemical Conversions of Compounds Modeling Oligophenylenes Containing Acenaphthylenyl and Acenaphthenyl Groups, A. I. Kovalev, T. N. Balykova, Sergey Lindeman, M. M. Teplyakov, I. A. Khotina, A. L. Rusanov, and Yu T. Struchkov

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Synthesis and crystal structure of 1,3,5-tris [4-(phenylethynyl)phenyl]benzene, Sergey Lindeman, Yu T. Struchkov, I. A. Khotina, V. N. Mikhailov, and A. L. Rusanov

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An m-Carboranedicarboxylic Acid Dianilide, Sergey V. Lindeman, Georgii A. Kats, and Lyudmila G. Komarova

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Structural Study of Compounds Modelling Elementary Polymer Units, 6. X-Ray Structural and Quantum-Chemical Investigation of the cis- and trans-isomeric Models of the Polynaphthoylenebenzimidazole Elementary Units, Sergey V. Lindeman, Igor I. Ponomaryov, Nikolai I. Raevsky, Yu T. Struchkov, and A. L. Rusanov

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5-Acetyl[2.2]paracyclophane, Sergey V. Lindeman, Yuri T. Struchkov, and Vyacheslav N. Guryshev

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N1-Acetyl-3'-methylandrosta-4,16-dieno[16,17-d]pyrazole-3-one, Sergey V. Lindeman, Alexandr I. Yanovsky, Ezequiel Huipe Nava, Alexey V. Kamernitzky, Alina V. Skorova, and Irina V. Vesela

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The Electrochemical Reduction of Iron Porphyrin Nitrosyls in the Presence of Weak Acids, Yanming Liu and Michael D. Ryan