The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 1989

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The Thermolysis of Dicarbonylcyclopentadienyliron Dimer: The Formation of Biferrocene, Charles A. Wilkie and Brian Huettl

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A Strategy for the Design of Flame Retardants: Cross-linking Processes, Charles A. Wilkie, Sunil J. Sirdesai, and Thitivat Suebsaeng

Submissions from 1988

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The Electrochemistry of Iron Porphyrin Nitrosyls in the Presence of Pyridines and Amines, In Kyu Choi and Michael D. Ryan

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Conformational Analysis of Colchicine and Isocolchicine by Molecular Mechanics, William Donaldson

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5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) Cations: Reactivity with Malonate Nucleophiles, William Donaldson and Muthukumar Ramaswamy

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Spectroscopic and Structural Characterization of the Nine-Coordinate Adduct of Tris(dipivaloylmethanato)europium(III) with 2,2':6',2"-terpyridine, Richard C. Holz and L. C. Thompson

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Molecular Structure of Dicumyl Peroxide, A. Yu. Kosnikov, V. L. Antonovskii, N. A. Turovskii, Sergey Lindeman, T. V. Timofeeva, Yu T. Struchkov, and I. P. Zyat'kov

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Electron Transfer Mechanism for β-lactam Antibiotic Action via Side-Chain Imine, Peter Kovacic, James R. Ames, and Michael D. Ryan

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Electrochemistry of the Anticancer Agents Methotrexate and α-Difluaromethylornithine in lminium Form, Peter Kovacic, James R. Ames, Edward C. Taylor, and Michael D. Ryan

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Anti-cancer Action of Metal Complexes: Electron Transfer and Oxidative Stress?, Peter Kovacic, William J. Popp, James R. Ames, and Michael D. Ryan

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Structural Study of Compounds Modelling Elementary Polymer Units, 5.† Molecular and Crystal Structures of C, C′-Disubstituted O-Carboranes, Sergey Lindeman, I. A. Khotina, M. M. Teplyakov, Yurii T. Struchkov, and Vasilii V. Korshak

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Dynamic Electrochemistry: Methodology and Application, Michael D. Ryan, George S. Wilson, and Dennis C. Johnson

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Interactions of Water-soluble Metalloporphyrins with Nucleic Acids Studied by Resonance Raman Spectroscopy, Jinghua H. Schneider, Junichi Odo, and Kazuo Nakamoto

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Reaction of Triphenylphosphine with Poly(ethylene terephthalate) and Certain Model Compounds at Elevated Temperature, Thitivat Suebsaeng, Charles Wilkie, and Charles E. Brown

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Azocoupling of o-Dinitrobenzene:Reactions of the Dianion and Anion-Radical with Aryldiazocations, Z. V. Todres, G. Ts. Ovsepyan, E. A. Ionina, A. Yu. Kosnikov, Sergey Lindeman, and Yu T. Struchkov

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Transformed Steroids. 171. Heterocyclization in the 16α,17α-Epiminopregn-5-ene-3β,21-diol-20-one series, A. M. Turuta, A. V. Kamernitskii, T. M. Fadeeva, A. Pabinger, V. S. Bogdanov, Sergey Lindeman, and Yu T. Struchkov

Submissions from 1987

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An Integrated Concept of Amebicidal Action: Electron Transfer and Oxy Radicals, James R. Ames, Ulrich Hollstein, Anré R. Gagneux, Michael D. Ryan, and Peter Kovacic

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Mode of Action of Antiprotozoan Agents. Electron Transfer and Oxy Radicals, James R. Ames, Michael D. Ryan, and Peter Kovacic

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Structure of l-Benzyl-2,2,3,3-tetramethyl-l-phenylphosphetanium Bromide, a Cyelobutane Derivative, J. A. Campbell, R. Larsen, C. Campana, and Sheldon E. Cremer

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Structure of l,l-Diphenylarsenanium Bromide Monohydrate, J. A. Campbell, R. Larsen, C. Campana, Sheldon E. Cremer, and A. Gamliel

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Cyclic Voltammetry of Quinolinium Salts and Related Compounds: Correlation with Structure and Anticancer Activity, Philip Walter Crawford, William O. Foye, Michael D. Ryan, and Peter Kovacic

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Charge Transfer-Oxy Radical Mechanism for Anticancer Agents: mAMSA Derivatives, Rhodamine 123, and Nickel Salicylaldoximate, Philip W. Crawford, Paavo Lumme, Hannu Elo, Michael D. Ryan, and Peter Kovacic

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Cleavage of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Formation of Olefins and α-methoxyolefins, William Donaldson

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Synthesis and Characterization of (Pentadienyl) (Tricarbonyl) Iron(+1) Cations, William A. Donaldson and Muthukumar Ramaswamy

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Catalytic Carbopalladation of ω-methylenebicyclo[n.1.0]alkanes, William Donaldson and Christine A. Brodt

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Electrochemistry of Nitrite Reductase Model Compounds. 3. Formation and Characterization of a Bis(hydroxylamine)(tetraphenylporphyrinato)Iron(II) Complex, Diwei Feng and Michael D. Ryan

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Electron Transfer-oxy Radical Mechanism for Anti-cancer Agents: 9-anilinoacridines, Peter Kovacic, James R. Ames, and Michael D. Ryan

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Structural study of compounds modelling elementary polymer units, 3.† Molecular and crystal structure of 1,3,5-tris[4′-(C-o-carboranyl)biphenyl-4-yl]benzene, Sergey Lindeman, Yurii T. Struchkov, V. E. Shklover, I. A. Khotina, and M. M. Teplyakov

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Structural study of compounds modelling elementary polymer units, 4.† Molecular and crystal structures of three isomers of 4,4′-bis(x-hydroxyphenoxy)octafluorobiphenyl, Sergey Lindeman, Yury T. Struchkov, Boris F. Malichenko, V. E. Shklover, Valerii E. Shklover, Tatiana M. Kameneva, and Evgenii V. Sheludko

Submissions from 1986

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Oxidative Ionic Metabolites of 1-Methyl-4-Phenyl-1,2,3,6- Tetrahydropyridine (MPTP): Correlation of Electroreduction with Physiological Behavior, James R. Ames, N. Castagnoli Jr., Michael D. Ryan, and Peter Kovacic

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Conjugated and Cross-Conjugated Mesomeric Betaines. Correlation of Electroreduction with Structure and Physiological Activity, James R. Ames, Kevin T. Potts, Michael D. Ryan, and Peter Kovacic

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Mechanism of Antibacterial Action: Electron Transfer and Oxy Radicals, James R. Ames, Michael D. Ryan, and Peter Kovacic

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Laser Desorption/Fourier Transform Mass Spectral Analysis of Various Conducting Polymers, Charles Eric Brown, Peter Kovacic, Charles A. Wilkie, Robert B. Cody, R. E. Hein, and James A. Kinsinger

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Polynuclear and Halogenated Structures in Polyphenylenes Synthesized from Benzene, Biphenyl, and p-Terphenyl under Various Conditions: Characterization by Laser Desorption/Fourier Transform Mass Spectroscopy, Charles Eric Brown, Peter Kovacic, Charles Wilkie, James A. Kinsinger, R. E. Hein, Stuart L. Yaniger, and Robert B. Cody Jr.

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Inhibition by Red Phosphorus of Unimolecular Thermal Chain-scission in Poly(methyl methacrylate): Investigation by NMR, FT-IR and Laser Desorption/fourier Transform Mass Spectroscopy, Charles Eric Brown, Charles Wilkie, Jeffrey Smukalla, Robert B. Cody Jr., and James A. Kinsinger

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Structure of l,l-Diphenylphosphorinanium Bromide Monohydrate, J. A. Campbell, R. Larsen, R. Ekeland, and Sheldon E. Cremer

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Charge Transfer Mechanism for Benzodiazepine (BZ) Action: Correlation of Reduction Potential of BZ Iminium with Structure and Drug Activity, Philip Walter Crawford, Peter Kovacic, Norman W. Gilman, and Michael D. Ryan

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Cyclic Voltammetry of Phenazines and Quinoxalines Including Mono- and Di-N-Oxides. Relation to Structure and Antimicrobial Activity, Philip W. Crawford, Richard G. Scamehorn, Ulrich Hollstein, Michael D. Ryan, and Peter Kovacic

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(3-Chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Preparation, Conformation, and Fluxional behavior, William Donaldson

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Reactivity of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Nucleophilic Attack by One or Two Equivalents of Malonate Anion, William Donaldson and Valerie J. Grief

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Electrochemistry of Nitrite Reductase Model Compounds. 2. Formation of an Iron Bis-Nitro Porphyrin Complex, John Baptista Fernandes, Diwei Feng, Andrew Chang, Amy Keyser, and Michael D. Ryan

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Charge Transfer-oxy Radical Mechanism for Anti-cancer Agents, Peter Kovacic, James R. Ames, Paavo Lumme, Hannu Elo, O. Cox, and Michael D. Ryan

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Charge Transfer Mechanism for Carcinogenesis by Alkylating and Other Agents, Peter Kovacic, Philip W. Crawford, Michael D. Ryan, and Victor C. Nelson

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Synthesis and Crystal Structure of a Macrocycle based on 4-cyanophenyl 4-Benzoylaminophenyl Ether, Sergey Lindeman, V. E. Shklover, Yu T. Struchkov, Igor I. Ponomarev, and S. A. Suing

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Molecular Structure of 4,16-dichloro- and 4,16-dibromo[2.2]-Paracyclophanes, Sergey Lindeman, Yu T. Struchkov, and Vyacheslav N. Guryshev

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Structure of 16α,17α-(Acetylepimino)Pregnenolone 3-Acetate in the Crystal and in Solution, A. M. Turuta, A. V. Kamernitskii, Sergey Lindeman, Yu T. Struchkov, M. Yu. Antipin, A. Yu. Kosnikov, V. A. Pavlov, and G. Snatzke

Submissions from 1985

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Charge Transfer and Oxy Radicals in Antimalarial Action. Quinones, Dapsone Metabolites, Metal Complexes, Iminium Ions, and Peroxides, J. R. Ames, Michael D. Ryan, D. L. Klayman, and P. Kovacic

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Laser Desorption/fourier‐transform Mass‐spectral Analysis of Molecular Weight Distribution and End‐Group Composition of Poly(p‐phenylene)s Synthesized by Various Routes, Charles Eric Brown, Peter Kovacic, Charles A. Wilkie, Robert B. Cody Jr., and James A. Kinsinger

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Response of Tissue Phosphate Content to Acute Dietary Phosphate Deprivation in the X-linked Hypophosphatemic Mouse, Charles Eric Brown, Charles A. Wilkie, Martha H. Meyer, and Ralph A. Meyer Jr.

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Reactivity of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: pd-allyl Cleavage, Synthesis of (±)-13-methyltridecanolide, William Donaldson and Barbara S. Taylor

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Electrochemistry of Nitrite Reductase Model Compounds. 1. Electrochemistry of Iron Tetraphenylchlorin, Diwei Feng, Yu-Shu Ting, and Michael D. Ryan

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Molecular Structure of 4,4′-Dimethoxydibenzoyl Peroxide, A. Yu. Kosnikov, V. L. Antonovskii, Sergey Lindeman, Yu T. Struchkov, I. P. Zyat'kov, G. A. Pitsevich, and V. I. Gogolinskii

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The Crystal Structure of Peroxydiglutaric Acid, Sergey Lindeman, Yu T. Struchkov, E. K. Starostin, and Gennady I. Nikishin

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Structure of a Solvated Nickel(II) Complex of (S)-2'-(N-benzylprolyl)aminoacetophenone and (R)-valine Schiff base, C25H29N3NiO3.1/2C4H8O. Conformational Calculation of Diastereomeric Complexes of (R)-valine and (S)-valine, Sergey V. Lindeman, T. V. Timofeeva, V. I. Maleyev, Yuri N. Belokon, M. G. Ryzhov, V. M. Belikov, and Yuri T. Struchkov

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Molecular Structure of N,N′-Bis(Phenylthio)-1,4-Quinodiimine, Sergey Lindeman, D. S. Yufit, V. E. Shklover, Yu T. Struchkov, V. A. Sergeev, V. I. Nedel'kin, and S. A. Arnautov

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Nontrivial Intramolecular Interaction in Ozonation of Dimethyl Ester of endo,cis-bicyclo[2,2,1]hept-5-en-2,3-dicarbonic acid in diethyl ether, Viktor N. Odinokov, Olga S. Kukovinets, Leonard M. Khalilov, Genrikh A. Tolstikov, A. Yu. Kosnikov, Sergey Lindeman, and Yu T. Struchkov

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Charge Transfer in the Mechanism of Drug Action Involving Quinoxaline Di-N-Oxides, Michael D. Ryan, Richard G. Scamehorn, and Peter Kovacic

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Structure of 3-acetoxy-16β,17β-cyclopropano-17α-pregn-5-en-3β-ol-20-one in the crystal and in solution, A. M. Turuta, L. Kohout, Sergey Lindeman, Yu T. Struchkov, A. V. Kamernitskii, and T. N. Deshko

Submissions from 1984

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The Structure of 1-tert-butyl-2,2,3,4,4-pentamethylphosphetane 1-oxide, C12H25OP, J. A. Campbell, C. N. Caughlan, A. Fitzgerald, C. Campana, and Sheldon E. Cremer

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Chloropalladation of 7-methylene-1-phenylbicyclo[4.1.0]-heptane: An Intermediate Containing Carbonium Ion Character, William Donaldson

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A Chronoamperometric Kinetic Study of the Reduction of the Double Fe4S4 Clustered Ferredoxin of Clostridium Pasteurianum by Methylviologen, Benjamin A. Feinberg, David D. Tuschel, and Michael D. Ryan

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Molecular and Crystal Structure of Hexazocyclane based on 4,4′-Diaminodiphenyl Ether, Sergey Lindeman, V. E. Shklover, Yu T. Struchkov, Igor I. Ponomarev, S. A. Siling, and S. V. Vinogradova

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Structural study of compounds modelling elementary polymer units, 1. Molecular and crystal structures of 1,3,5-tris(4-biphenylyl)-benzene and 1,3,5-tris[4-(C-o-carboranylmethyl)phenyl]benzene, Sergey Lindeman, Valerii E. Struchkov, Yurii T. Struchkov, I. A. Khotina, Tunzil M. Salykhnova, M. M. Teplyakov, and Vasilii V. Korshak

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The X-ray Investigation of 16α,17α-Thiazolidine Derivatives of Δ4- and Δ5-Pregnanes and Conformational Analysis of their Oxathiolane Analog, Sergey Lindeman, T. V. Timofeeva, V. E. Shklover, Yu T. Struchkov, A. M. Turuta, and Alexey V. Kamernitzky

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Refinement of the Structure of sym-triphenyltriazine, Sergey V. Lindeman, V. E. Shklover, Yu T. Struchkov, L. M. Mitina, and V. A. Pankratov

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Friedel‐Crafts Catalysis of Polyaromatic Char Formation During Pyrolysis of Poly(ethylene terephthalate) and Poly(1,4‐butylene terephthalate), Thitivat Suebsaeng, Charles A. Wilkie, Vern T. Burger, Janet Carter, and Charles Eric Brown

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Solid Products from Thermal Decomposition of Polyethylene Terephthalate: Investigations by CP/MAS 13C NMR and Fourier Transform-IR Spectroscopy, Thitivat Suebsaeng, Charles Wilkie, Vern T. Burger, Janet Carter, and Charles Eric Brown

Submissions from 1983

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Characterization of the Solid Components of Biological Tissue by Cross Polarization, Magic Angle NMR Spectroscopy, Charles Eric Brown and Charles A. Wilkie

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Crystal Structure of Peroxydisuccinic Acid, Sergey V. Lindeman, V. E. Shklover, Yu T. Struchkov, E. K. Starostin, and Gennady I. Nikishin

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Antiferromagnetic Complexes with Metal-metal Bonds ☆: IX. Synthesis and Molecular Structures of Methylcyclopentadienylchromium(III) Sulfide Diamagnetic Tetramer and the Antiferromagnetic Copper(II) Bromide Adduct of the Tetranuclear Cluster (MeC5H4)4Cr43-O)(μ3-S)3, A. A. Pasynskii, I. L. Eremenko, Yu. V. Rakitin, V. M. Novotortsev, O. G. Ellert, V. T. Kalinnikov, V. E. Shklover, Yu T. Struchkov, Sergey Lindeman, T. Kh. Kurbanov, and G. Sh. Gasanov

Submissions from 1982

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The Electron-Transfer Kinetics of Spinach Ferredoxin with Strong Reductants, Sipra Ray Dasgupta and Michael D. Ryan

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Mechanism of Formation of (.eta.3-oxocyclobutenyl)cobalt Compounds from [Co(CO)4]- and Cyclopropenium Cations, William Donaldson and Russell P. Hughes

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Syntheses of Cationic and Zwitterionic Cyclobutadiene Compounds of Cobalt(I). Crystal and Molecular Structure of Tricarbonyl(.eta.-1-methoxy-3-methyl-2-phenylcyclobutadiene)cobalt(1+) Hexafluorophosphate, William Donaldson, Russell P. Hughes, Raymond E. Davis, and Steven M. Gadol

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The Reduction of Cytochrome C by Iron EDTA-Like Complexes: Implications on Charge Effect Corrections to Mediator-Protein Rate Constants, Jing-Fong Wei and Michael D. Ryan

Submissions from 1981

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A Convenient Synthesis of 2-Alkyl-3-Deutero-2-Cyclopropene-1-Carboxylic Acids, William Donaldson and Russell P. Hughes

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Molecular Interpretation of Kinetic-Ionic Strength Effects, Benjamin A. Feinberg and Michael D. Ryan

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Crystal and Molecular Structures of the two Crystalline Modifications of N-Salicylidene-Pentafluoroaniline, Sergey Lindeman, V. G. Andrianov, S. G. Kravcheni, V. M. Potapov, K. A. Potekhin, and Yu. T. Struchkov

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Triphase Catalysis. Influence of Percent Ring Substitution on Active-Site Mobility, Macroenvironment, and Efficiency, Noritaka Ohtani, Charles Wilkie, Alok Nigam, and Steven L. Regen

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Studies of the EE Mechanism. Evidence for Reversible Dimer Formation in Electrochemical Oxidation of a Cyclic Dithioether, Michael D. Ryan, Dale D. Swanson, Richard S. Glass, and George S. Wilson

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Pyrolysis Reactions of Poly(methyl methacrylate) and Red Phosphorus: An Investigation with Cross‐Polarization, Magic Angle NMR Spectroscopy, Charles A. Wilkie, Jay W. Pettegrew, and Charles Eric Brown

Submissions from 1980

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Electrochemical Approaches to the Study of Small Molecule-Protein Reaction Rates, Sipra Ray Dasgupta and Michael D. Ryan

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A Carbon-13 Nuclear Magnetic Resonance Study of Some Pentanedionato Complexes of Silicon and Germanium, Daniel T. Haworth, Gong-Yu Lin, and Charles Wilkie

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The Solid State 13C-NMR Spectra of Some Intercalation Compounds, Daniel T. Haworth and Charles A. Wilkie

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A 13C NMR Study of Trans-tris(trifluoropentanedionato)aluminum(III), Gong-Yu Lin, Charles A. Wilkie, and Daniel T. Haworth

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The Electrochemical Oxidation of Substituted Catechols, Michael D. Ryan, Alice Yueh, and Wen-Yu Chen

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The Use of Rotating Disk Voltammetry for the Determination of Homogeneous Small Molecule-Redox Protein Reaction Rates, Jing-Fong Wei and Michael D. Ryan

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Halocyanophosphines P(CN)yX3-y and Related Cyanophosphine Derivatives, Charles Wilkie and R. W. Parry

Submissions from 1979

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Cationic Cobalt(I) Carbonyl Compounds Containing Complexed Cyclobutadienes, Christopher E. Chidsey, William Donaldson, and Russell P. Hughes

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Interactions of Small Organic Rings with Transition Metals. Formation of .eta.3-cyclobutenonyl Complexes by the Ring Expansion of 2-cyclopropene-1-carbonyl Metal Species, Christopher E. Chidsey, William Donaldson, Russell P. Hughes, and Paul F. Sherwin

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Reductive Acetoxylation on .alpha.,.alpha.'-dibromocycloalkanones by Ultrasonically Dispersed Mercury, Albert J. Fry, William Donaldson, and Geoffrey S. Ginsburg

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Impregnated Reagents. Characterization of Sodium Cyanide on Alumina, Steven L. Regen, Silvio Quici, and Michael D. Ryan

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The Chronoamperometric Determination of Homogeneous Small Molecule-Redox Protein Reaction Rates, Michael D. Ryan, Jing-Fong Wei, Benjamin A. Feinberg, and Ying-Kit Lau

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Carbon and Phosphorus Relaxation in Some Phenylphosphorus Compounds, Charles A. Wilkie

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The Solid State 13C-NMR and 19F-NMR Spectra of Some Graphite Fluorides, Charles A. Wilkie, Gong-Yu Lin, and Daniel T. Haworth

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A 13C-NMR and Infrared Investigation of Dihalobis-(2,5-pentadionato) tin (IV) Complexes, Charles Wilkie, Gong-Yu Lin, William R. Snyder, and Daniel T. Haworth

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Electrochemical Oxidation of Some Mesocyclic Dithioethers and Related Compounds, George S. Wilson, Dale D. Swanson, Jacob T. Klug, Richard S. Glass, Michael D. Ryan, and W. Kenneth Musker

Submissions from 1978

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Additional NMR Data on Compounds of the Type cis-Ti(AA)2X2, Daniel T. Haworth, Gongyu Lin, and Charles A. Wilkie

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The Solid State 13C-NMR Spectra of Some Carbides, Daniel T. Haworth and Charles A. Wilkie

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Review of Electrochemistry of Biological Molecules, Michael D. Ryan

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The Effect of Slow Two‐Electron Transfers and Disproportionation on Cyclic Voltammograms, Michael D. Ryan